Lecture 4 Flashcards
What is K in the Arrhenius Rate Law?
the rate constant
What does the rate constant mean?
the frequency of collisions resulting in a reaction
What is T in the Arrhenius Rate Law?
absolute temperature in Kelvins
What is A in the Arrhenius Rate Law?
the pre-exponential factor, a constant for each chemical reaction
What is Ea in the Arrhenius Rate Law?
the activation energy for the reaction (in the same units as RT)
What is R in the Arrhenius Rate Law?
universal gas constant
What is the Arrhenius Rate Law equation?
K=Ae^(-Ea/RT)
In the Arrhenius Rate Law explains what happens to the other variables when Temperature increases?
(Ea/RT) decreases
(-Ea/RT) increases
lnk increases
K increases
kf and kr increases
Rate constants (kf and kr) typically only increase when ___ is increased?
temperature
Can Kc increase or decrease?
it can both increase or decrease depending on if the reaction is endo or exothermic
Describe deltaHr when a reaction is exothermic?
deltaHr<0