Lecture 3 Flashcards
Element
A chemical element is the simplest form of matter to have unique properties Each element is identified by an atomic number, the number of protons in its nucleus i.e. Water has unique properties but it can be broken down into two elements, H and O that have unique properties of their own
Protons, neutrons and electrons
Protons have a single positive charge; weighs approximately 1amu Neutrons have no charge; weighs approximately 1amu Electrons have a single negative charfe and very low mass (1836 electrons = 1amu)
Isotopes and radioactivity
Isotopes are elements that differ from one another only in number of neutrons and therefore in atomic mass
- Although different isotopes of an element exhibit identical chemical behavior, they differ in physical behavior, many are unstable and decay to more stable isotops by giving off radiation i.e. 1H (Hydrogen), 2H (Deuterium) and 3H (Tritium) Radioactivity the process of decay of unstable isotopes (radioisotopes)
- Each radioisotope has a characteristic physical half life, the time required for 50% of its atoms to decay to a more stable state
Ions
Ions are charged particles with unequal numbers of protons and electron An ion can consist of a single atom with a positive or negative charge or it can be as large as a protein with many charges on it Ions form because elements with 1-3 valence electrons tend to give them up and those with 4-7 electrons tend to gain more Ionization -the process when an atom transfers electsons from one to another and turn both of them into ions
Ions - anion
Anion - the particle that gains electrons acquires a negative charge
Ions - cation
Cation - the particle that loses electrons acquires a positive charge (because it then has a surplus of protons)
Chemical bonds
Covalent Ionic Hydrogen Van der Waals forces
Chemical bonds - Covalent
- Sharing of one or more pairs of electrons between nuclei Nonpolar covalent bond- the strongest of all chemical bonds; when shared electrons spend approximately equal time around each nucleus Polar covalent bond- If shared electrons spend significantly more time orbiting one nucleus than they do the other, they lend their negative charge to the region where they spend the most time i.e. H-O, electrons are more attracted to the O and makes that region of the molecule slightly negative and the H region slightly positive
Chemical bonds - Ionic
Is the attraction of a cation to an anion, but no sharing of electrons i.e. Sodium (NA+) and Chloride (Cl-) ions are attracted to each other and form the compound sodium chloride (NaCl)
Chemical bonds - Hydrogen
- A Weak attraction between a slightly positive H atom in one molecule and a slightly negative O or N atom in another
- H bonds also form between different regions of the same molecule, esp in very large molecules such as protein and DNA; they cause such molecules to fold or coil into precise 3D shapes i.e. H2O are weakly attracted to each other by H bonds
Chemical bonds - Van der Waal forces
- Are weak, brief attractions netween neutral atoms
- Oppositely charged regions of two atoms attract each other for a very short instant in time
- A single van der Waals forces is only about 1% as strong as a covalent bond, but when two surfaces or large molecule meet, they van der Waal forces between large numbers of atoms can create a strong attraction i.e. plastic wrap clings to food and dishes; a gecko can run up a windowpane