Lecture 15 Flashcards

1
Q

Ketone with…..LDA,RMGX,NAOH,CO3

A

Complete enolate
NA
PE..WITH SC
NO

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Ester with…..LDA,RMGX,NAOH,CO3

A

CE
NS
NS+PE AND SC
NO

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

ACYL CHLORIDE WITH…LDA,RMGX,NAOH,NET3

A

Ns
NS
NS
REQUIRED MASKING

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

ALDEHYDE WITH……LDA,RMGX,NAOH,CO3

A

PE+SC…..NA
NA
PE+SC
NO

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Reaction of cyanide with….lda,rmgx,naoh

A

CE
NA
PE

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Carboxylic acid, amide = lDA OR NAOH
Carboxylic acid +acidic enolization =

A

Strong base like lDA,but not NAOH
Racemization, selfisomerization

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

How many lDA requrie for alkylation of aceticacid

A

The formula is no.of acidic alpha hydrogen +1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Acidity order
Reactivity order
A. Oh
B. NH
C. CH

A

Acidity order….a>b>c
Reactivity order…..c>b>a

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Name of non nucleophilic base

A

Lda ki puri family
Na,k
R3N,tbuo-k+,co32-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Nucleophilic bases name

A

GR
NH3,NH2-
OH-/OR-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly