Lecture 15 Flashcards
Give the equation for the entropy of a system
S = entropy
∂G = change in Gibbs free energy
∂T = change in temperature
Give the equation for the difference in entropy between the superconducting and the normal to the state
∆S = change in entropy
∂G = change in Gibbs free energy
∂T = change in temperature
B = magnetic flux = 0
B_c = critical flux
When does the change in entropy for a system equal 0? Why?
At the Curie temperature because the critical field equals 0 at this point.
Why isn’t there any latent heat for the transition from the normal to the superconducting state?
Because this transition occurs without a discontinuity in entropy.
Give the equation for the difference in the specific heat at constant volume between the superconducting and the normal
∆C_v = change in specific heat
T = temperature
∆S = change in entropy
B_c = magnetic flux
Give the equation for the difference in the specific heat at constant volume between the superconducting and the normal to the state at the Curie temperature
∆C_v = change in specific heat
T = temperature
B_c = magnetic flux
Describe the graph of specific heat against temperature for a superconducting and a normal state
There is a sharp rise in the specific heat at the Curie temperature of a superconductor due to the onset of ordering of the conduction electrons.
Describe the graph of the resistivity and the specific heat against T/T_c for a superconductor
Give the equation for electronic specific heat
C_v-el = electronic specific heat
C0 = constant
E_g = bandgap energy ~ (7/2)(k_B)(T_c)
T = temperature
What range is the electronic specific heat equation valid for?
The electronic specific heat presents the same behaviour as the number of _______ and _____ in a semiconductor.
Electrons
Holes
Describe the graph of electronic specific heat against 1/T
Compare the energy bands of a semiconductor to the energy states of a superconductor
They are equivalent
How can the energy gap of a semiconductor be measured?
By measuring photon absorption
How can the bandgap of a superconductor be measured?
By measuring microwave photon absorption (as the bandages are only a few meV).
What does the BCS theory of superconductivity explain?
- Attraction between pairs of electrons.
- How bound electron ‘Cooper pairs’ can form.
- How Cooper pairs can form a collective ground state of lower energy than that of the normal electron states.
What are Cooper pairs?
Composite bosons made of bound electron pairs. They are formed by attraction between electrons via a lattice.
Describe the interaction between two electrons in free space
There is a strong Coulombic repulsion