Lecture 1 Flashcards
What are the two kinds of physical behaviours at the molecular level?
Microphysical processes and Macrophysical processes.
What does Microphysical properties mean?
This is based on the individual behaviours of single small particles like atoms, molecules and supramolecular structures. These processes are mostly stochastic.
What does Macrophysics properties mean?
The kind of behaviour of large bodies. This is based on the laws of classical physics for example classical mechanics. The behaviour for macrophysical systems are generally deterministic.
What is the difference between macrophysical and microphysical processes?
To explain the difference, let us consider a mechanical wheelwork. Due to its design and construction we can predict the behaviour of the system. This prediction is based on the laws of classical mechanics. In contrast to this, a chemical reaction with a small number of molecules in a homogeneous phase depends on stochastic collisions of the individual molecules with each other. Because this process is stochastic, the prediction can only be made in a statistical way.
What does stochastic mean?
Random events having a certain probability of taking place, however, each separate event cannot be predicted in a determined way.
What does supramolecular structures mean?
Assemblies of several molecules in a complex that carry out certain processes, No strong molecular bonds, just kept together by weak forces (Van Der Waals forces, hydrophobic forces and electrostatic forces)
What does anisotropic and isotropic mea?
Anisotropic is the limitation of the degrees of freedom of a biochemical reaction is realised by a property of the system which is called anisotropic. In anisotropic systems, the mobility of molecules in various directions is not identical, some directions are restricted and some are promoted.
What is an effective parameter?
Parameters used in the “microphysical world” and can be measured with arbitrary exactness. However, these parameters do not correspond to some visible boundaries.