Le Chats Princi Flashcards

1
Q

What is le chats principle

A

“If an external stress is applied to a system at equilibrium, the system adjusts itself in such a way that the stress is partially offset.”

“If a change is imposed on a system at equilibrium, the position of the equilibrium shifts in direction to counteract the change.”

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2
Q

What happens to reaction quotient (Q) if reactant or product are removed/added to a reaction at equilibrium

A

Q no longer equal the equilibrium constant

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3
Q

If volume is decreased what does reaction do

What if increased

A

The pressure increases so it goes to side with fewer moles gas

Pressure decreases so it goes to side with greater moles gas

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4
Q

If temp increases where does equilibrium shift

what if decreases

A

IDK

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5
Q

What do catalysts do

A

Not consumed or produced during rxn
Do not affect enthalpy change of rxn

Do Affect rate of rxn, help reach equilibrium faster but does not change the position of equilibrium

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6
Q

When can we use small x approx
How do you check if the approx is valid

A

When k is very small (<10^-3)

X value you calculate/the initial concentration

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