Laws Flashcards
Law of Mass action
when applied to elementary reaction - rate of reaction is proportional to the molar amount (concentration or partial pressure) of each reactant raised to the power of its reaction order
2H2 + O2 –(K1) –> 2H2O
Rate = K1(P(H2))^2(P(O2))
Pauli exclusion principle
no two electrons in an atom can have the same set of quantum numbers
aka within orbitals, electrons must be opposite spin
Boyle’s Law
pressure of gas is inversely proportional to the volume it occupies
Henry’s Law
amount of gas dissolved in a liquid is proportional to the partial pressure of the gas
P=kC
p= pressure of gas
k= henry’s law constant
c=concentration of gas
Heisenberg uncertainty principle
the exact position and momentum of a particle cannot both be known at the same time
the uncertainty of position and moment are inversely proportional: the more accurate the position is known, the less accurate its momentum can be known
instead electrons are found within a probability distribution of where they most likely will be found
nuclear force
attractive force that binds neutrons and protons in the nucleus
because protons and neutrons are approximately the same mass, they are influenced similarly by the nuclear force
experimental control
measurement of all experimental conditions without independent variables
allows baseline measurements of dependent variables without independent variables
colligative properties
affected by amount not by identity of the solute
for example: Rault’s law is that by adding more solute you will reduce the number of solute solvent intermolecular interactions because will decrease the concentration of the solvent which is a colligative property.
ex: Freezing point is affected by amount of solute, not by the reactivity of it which is a chemical property