lastmin Flashcards
Fractional Distillation stages
1-Crude Oil is heated to a very high temperature causing the crude oil to boil so all the Hydrocarbons evaporate and turn into a gas
2-Crude Oil Vapour is then fed into the fractional distillation column , the column is hotter at the bottom and cooler at the top .
3- Hydrocarbon vapours now rise up the column, the hydrocarbons condense when they reach their boiling point and then the liquid fractions are removed. The remaining hydrocarbons continue moving up the column and these condense when they reach their boiling point.
Fractions contain hydrocarbons with a similar number if carbon atoms. Some fractions are used as fuels. What is petrol and diesel use to do
fuel cars
Fractions contain hydrocarbons with a similar number if carbon atoms. Some fractions are used as fuels. What is kerosene used as
jet fuel
Fractions contain hydrocarbons with a similar number if carbon atoms. Some fractions are used as fuels. What is heavy fuel oil
to power
Fractions contain hydrocarbons with a similar number if carbon atoms. Some fractions are used as fuels. What is liquified petroleum gases used in
camping stoves
Some fractions are used as Feedstock for the petrochemical industry. What chemicals are feedstock used to make?…(4)
Solvents
Lubricants
Detergents
Polymers
What is cracking
Cracking is a process in which long chain alkanes are broken down (cracked) to produce smaller, more useful molecules
Long chain Hydrocarbons are not very flammable and this is one reason why they do not make good fuels. Why is this a problem
Because there is a high demand for short-chain hydrocarbons to be used as fuels
name the two ways to carry out cracking
Catalytic Cracking and Stream Cracking
what we use in catalytic cracking
We use high temperatures and a catalyst.
what we use in steam cracking
We use high temperature and steam
what does cracking make
Cracking makes hydrocarbons called alkenes
Alkenes are very useful molecules, why?
Used to make chemicals called polymers
also used as the starting material for other useful chemicals as well
Well, alkenes are MORE reactive than alkanes and we can use this idea to test for alkenes…how do you test for alkenes?
We test for alkenes using bromine water which is orange. If we shake our alkene with bromine water then bromine water turns colourless
how to calculate the mean rate of reaction
mean rate of reaction = quantity of product formed/time taken
what is a pure substance
A pure substance is a substance not mixed with any other substance
what is the simplest way to determine if a substance is pure or not
To simply measure its melting point and boiling point.
A pure substance melts at a specific fixed temperature.
A pure substance also has a specific fixed boiling point.
Impure substances melt and boil over a range of temperatures.
What is a formulation
A formulation is a complex mixture that has been designed as a useful product
In a formulation, the quantity of each component is carefully measured so that the product has the properties we need.
Formulations include…(name 7)
FUELS CLEANING PRODUCTS PAINTS MEDICINES ALLOYS FERTILISERS FOODS
What are 4 ways to separate mixtures/physical separation techniques
FILTRATION
CRYSTALLISATION
DISTILLATION
CHROMATOGRAPHY
Gases in the atmosphere?
78 percent nitrogen
21 percent oxygen
small proportions of other gases eg carbon dioxide, water vapour and noble gases such as argon
what is carbon footprint
The total amount of C02 and other greenhouse gases emitted over the full life cycle of a product, service or event
what do we use resources for
For warmth, shelter, food and transport.
In many cases these resources are produced by agriculture (farming) eg cotton is produced from a plants
what i s Potable water
Potable water is water that is safe to drink
why is potable water not the same as pure water?
Because pure water in the chemical sense contains no dissolved substances at all but potable. water dies - but in small amounts
where crude oil found
in rocks
what kind of resource is crude oil
finite
what is crude oil
a mixture of molecules called hydrocarbons
what are hydrocarbons
molecules made of hydrogen and carbon atoms only
alkanes
hydrocarbons with the general formula C2H2n+2
List Alkanes in order
Methane
Ethane
Propane
Butane
MEPB
What are alkanes and why
plus ps what does saturated mean
Alkanes are saturated molecules because the carbon atoms are fully bonded to hydrogen atoms
Because the carbon atoms are fully bonded to the hydrogen atoms
Saturated on general means something has bonded as many times as possible aka no more (C-C can be made)
In specific here, saturated means the carbons atoms are fully bonded to the hydrogen
3 properties of hydrocarbons
Viscosity - tells us thickness of a fluid
Size of HC molecules increases, Viscosity increase
Flammability - tells us how easily a hydrocarbon combusts
Increases decreases
Boiling point - the temperature at which a liquid turns to a gas
Increases increases
Examples of where hydrocarbons can be used as fules
ships
planes
cars
these all run on Hydrocarbon fules
when do Hydrocarbons release energy and how
When combusted (burnt).
During combustion, Carbon and Hydrogen atoms in fuel react with oxygen . The carbon and hydrogen are oxidised.
If oxygen is unlimited, the reaction produces carbon dioxide and water - this is Complete combustion.
Complete combustion =
Hydrocarbon + oxygen —-> carbon dioxide + water
for hydrocarbons in crude oil ( a naturally occurring petroleum product) to be useful, what must we do?
Separate them - to do that we use a technique called fractional distillation
In Fractional distillation, crude oil is separated into fractions. Fractions contain hydrocarbons with a similar number of carbon atoms.
Fractional distillation separates crude oil into simpler, more useful mixtures. The method can be used because different hydrocarbons have different boiling points.
long chain hydrocarbons have long chain boiling points. Where are these removed in fractional distillation?
From the bottom of the column.
Very short chain hydrocarbons have low boiling points and these do not condense - they are removed from where as what in fractional distillation?
Removed from the top of the column as gases
some fractions are used as feedstock for the petrochemical industry, what is a feedstock?
A chemical that is used to make other chemicals
to solve the problem of a demand of shorter chained hydrocarbons, what do we do?
We use cracking!!!
what does cracking make
Hydrocarbons called alkenes
alkanes have a single bond between two carbon atoms, what do alkenes have?
A double bond between two carbon atoms
what is petrochemical
a substance made from crude oil using chemical reactions
When we plot quantity of product formed (grams) on y axis and time in x axis, initially the reaction is fast why?
Because we are making a lot of product in a short amount of time. That is because we have a large number of reactant molecules so lots of them are reacting and forming products.
When we plot quantity of product formed (grams) on y axis and time in x axis, gradually, the slope of the line becomes less steep, telling us that the reaction is slowing down. Why
Because the rate of reaction is decreasing, meaning a lot of the reactants have turned into product, meaning there are fewer reactant molecules available to react.
When we plot quantity of product formed (grams) on y axis and time in x axis, at the end of the line, the slope of the line is now zero - the line is flat so the reaction has stopped… Why?
Because all the reactant molecules have already reacted.