Last Resort ππ Flashcards
Neopentane is
2,2- dimethylpropane
1 mole of any gas at STP occupied how much volume?
22.4L
Atomic spectrum of hydrogen
SERIES n1 spectral region
- Lyman 1 UV
- Balmer 2 Visible
- Paschen 3 Infrared
- Brackett 4 Infrared
- Pfund 5 Infrared
- Humphrey 6 Far infrared
Rydberg formula for hydrogen
1/ Ξ» = Rβ (1/nβΒ² - 1/nβΒ²)
-Rβ: rydberg constant
-nβ:energy level
Possible number of spectral lines when an electron returns from
nβ ββΊ nβ
(nβ - nβ)(nβ - nβ +1)/ 2
What are isoelectronic species?
Any two or more atoms, ions, or molecules that have the same number of electrons
Molecular orbital order for atoms having Z β€ 7
Ο(1s) < Οβ(1s) < Ο(2s) < Οβ(2s) < Ο(2p_x) = Ο(2p_y) < Ο(2p_z) < Οβ(2p_x) = Οβ(2p_y) < Οβ(2p_z)
Molecular orbital order for atoms having Z β₯ 8
Ο(1s) < Οβ(1s) < Ο(2s) < Οβ(2s) < Ο(2p_z) < Ο(2p_x) = Ο(2p_y) < Οβ(2p_x) = Οβ(2p_y) < Οβ(2p_z)
Electron withdrawing groups
- NO2
- CN
- COOH
- CHO
- CONH2
What is a heterocyclic compound?
cyclic compound that has atoms of at least two different elements as members of its ring
What is electron gain enthalpy?
Electron gain enthalpy of an element is the energy released when a neutral isolated gaseous atom accepts an extra electron to form the gaseous negative Ion i.e. anion.
Stationary phase in paper chromatography
Water
How is conjugate acid formed?
By accepting a proton (H+)
Angular nodes
planar areas around the nucleus where the probability of finding an electron is zero
- s: 0
- p: 1
- d: 2
- f: 3
Shape and hybridization of BF3 molecule
- Trigonal planar
- spΒ²
F | B / \ F F
In kjeldahls method, nitrogen in the organic compound is quantitatively converted to
Ammonium sulphate
(NHβ)βSOβ
Dipole moment of BFβ
Zero
Because the resultant of any two bonds is equal and opposite to the third bond
Metamerism
When bridging function groups are present. Likeβ¦
-O-
-CO-
-COO-
-NH-
Tautomerism
- When =C (spΒ²) is present
- atleast 1 Ξ± Hydrogen atom
De broglie wavelength
Ξ» = h/β (2mKE)
m: mass
h: plancks constant
KE: kinetic energy
Amino acid which is not optically active
Glycine
Reducing sugars example
- glucose
- fructose
- maltose