Lab 4 Flashcards
Which of these properties is determined without changing the identity of the substance, physical or chemical properties?
Physical properties
In chemical properties, the compounds change their composition
Difference between intensive and extensive physical properties
Intensive
Properties that are not affected by the amount of matter
Ex: colour, m.p, b.p, density
Extensive
Properties that are affected by the amount of matter
Ex: mass, volume, length, shape
Physical properties
The property of a pure compound that helps in its identification.
A compound can have different Physical Properties like:
Colour (S,L)
Melting Point (S)
Sublimation (S)
Boiling Point (L)
Freezing Point (L)
Refractive Index (L)
Density (L)
Odour (S,L)
Hardness (S)
Solubility (S,L)
Melting point
It is the temperature at which a solid compound changes state from solid to liquid at 1 atmospheric pressure.
At the melting point, the solid and liquid phase exists in equilibrium.
Melting point range
The difference between the temperature at which the collapse of solid crystals is first observed and the temperature at which the solid sample becomes completely liquid.
It should not exceed more than 1°C.
Difference between pure and impure/ crude compounds
Pure compounds - melts over a narrow range
Impure/ crude compounds - melts over a widerange
Boiling point
The boiling point of the liquid is the temperature at which the pressure of the vapour is equal to the atmospheric pressure (1 atm. pressure or 760 mm Hg).
Relation between the boiling point (temp.) and the pressure
Directly proportional
a liquid will boil at a higher temperature when the external pressure is higher and will boil at a lower temperature when the external pressure is reduced.
B.P. of Water
B.P. of Ethanol
B.P. of Diethyl ether
B.P. of Water = 100°C
B.P. of Ethanol = 78.5°C
B.P. of Diethyl ether = 34.6°C
Change of energy forms at the boiling point
From heat energy to kinetic energy
Effect of Vapour pressure on Boiling point
Boiling point of a liquid is directly proportional to vapor pressure.
Sublimation
a process that involves the direct conversion of a solid to a gas without passing through the liquid state.
Melting point apparatus
Analogue
Function of the boiling chips
Prevent excess boiling