lab 3 Flashcards
The change in the concentration of reactant or product with time is used to calculate this.
reaction rate
The reaction rate depends on a variety of factors including temperature and concentrations of reactants.
This shows the mathematical relationship between reaction rate and the concentrations of species upon which the rate depends.
rate law (rate equation)
For a generic equation aA + bB cC + dD, the form of the rate law may be rate = k[A]m[B]n.
The exponents m and n are generally 0, 1 or 2. These exponents are experimentally determined.
The sum of the exponents in the rate law
reaction order
This indicates the number of molecules or ions involved in the rate-detmining (slow) step of the reaction
A substance that increases the rate of a chemical reaction without itself being consumed.
Catalyst
The catalyst increases the rate of reaction by forming a complex with a reactant that is more reactive than the reactant itself.
The minimum amount of energy needed to initiate a chemical reaction.
Activation Energy
The activation energy is characteristic of the reaction and does not vary significantly with temperature
This shows the dependence of the rate constant of a reaction on temperature.
Arrhenius equation
A, the preexponential factor, is constant
E,a the activation energy, is constant
R is the ideal gas constant
T, is temp in kelvin
A proportionality constant between the reaction rate and the concentrations in the rate law.
rate constant, k