(L5) Module 1 L5 - Acids and bases Flashcards

1
Q

What’s the 1st kind of chemical reaction?

A

electron transfer

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2
Q

What’s the 2nd kind of chemical reaction?

A

precipiation

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3
Q

What’s the 3rd kind of chemical reaction?

A

acid-base

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4
Q

What is a lewis base?

A

electron-pair donator?

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5
Q

What is a lewis acid?

A

electron-pair acceptor

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6
Q

What is a coordinate/dative bond?

A

When both atoms share the electrons that only come from 1 of the atoms.

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7
Q

Bronsted-Lowry acid definition

A

proton (h+) donor

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8
Q

Bronsted-Lowry base definition

A

proton (h+) acceptor

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9
Q

What are the bronsted-lowry acid/base definitions for (conditions)

A

acid/base behaviour in an aqueous solution

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10
Q

what is a conj acid/base pair?

A

2 species which differ by a proton

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11
Q

What is an acid?

A

Proton attatched to an extremely electronegative atom (F, O, N) via a polar bond.

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12
Q

What are strongest atoms attatched to?

A

halogen (group17) or oxygen (group16) (F, O , N)

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13
Q

What is a base?

A

atleast 1 lone pair of electrons. usually group 15, 16, 17.

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14
Q

What forms strongest bases?

A

Formed from deprotonation of molecules containg X-H bonds, where X is a group 15 or 16 element.

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15
Q

What is a electrophile? Nucleophile?

A

electrophile, loves and accepts electrons
nucleophiles is a electron donator

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16
Q

how to use H3O conc to find pH?

A

ph= -log [H3O]

in neutral water pH=7 pOH=7

17
Q

how to use OH conc to find pOH?

A

pOh= -log [OH]

in neutral water pH=7 pOH=7

18
Q

What is the equilibrium process associated w/ Kw?

A

Kw, auto-ionisation constant of water

19
Q

What does [H3O] equal in neutral water?

A

Kw = [H3O] = [OH] =1.010-7 mol L-1
or Kw = 1
10-14

20
Q

what is conc [H3O] using pH?

A

[H3O] = 10^-ph

21
Q

pKw equation?

A

pKw = -log(Kw)
= 14 : at 25 Celcius

22
Q

Ph +pOH =

A

14

23
Q

Kw = [H3O][OH] how to find [OH]?

A

[OH] = Kw/[H3O]

24
Q

How does temperature effect Kw?

A

Temperature decreases at Kw.

25
Q

Why must we be careful what we refer to as acidic, neutral, basic?

A

Might usually think of a solution with pH of 6.6 as slightly acidic. At 35 celcius it is neutral.
This is because at neutral [H3O] = [OH]

26
Q

What undergoes complete dissociation?

A

Electrolytes.. such as ionic solids, acids, bases.

27
Q

What’s a strong acid?

A

Acids which completely dissociate and donate their protons.

28
Q

What’s an example of stong acids?

A

HCl (hydrochloric, present in gastric acid),
H2SO4 (sulfuric), HNO3 (nitric), HBr (hydrobromic), HI (hydroiodic),
HClO4 (perchloric)

29
Q

How to calculate concentration from a strong acid?

A

1:1 scale.

30
Q

What’s a strong base?

A

Bases which generate OH- in reactions which go to completion

31
Q

How to calculate concentration from a strong base?

A
32
Q
A