L6 Flashcards
-………is material of no value for the owner and which the owner wants to discard
……….is a waste in a solid state.
-Waste
-Solid Waste
is a waste with properties that make it dangerous or capable of having a harmful effect on human health and/or the environment.
Hazardous Waste
Hazardous waste properties
1-gnitability
2-Corrosivity
3-Reactivity
4-Toxicity
are wastes that can readily catch fire and sustain combustion.
:-Ignitable wastes
1-Liquid wastes; that have a flash point less than 60°C
2-Solid wastes; that, under standard temperature and pressure, can cause fire through friction or spontaneous chemical changes and, when ignited, burn so vigorously
can readily corrode or dissolve flesh, metal or other materials
:-Corrosive wastes
Example: aqueous wastes with a pH of 2.0 units or below or of 12.5 units or above
A solid waste that exhibits any of the following properties is considered a hazardous waste due to its……………..:
Forms an explosive mixture with water
Generates toxic gases when mixed with water
Contains cyanide or sulfide and generates toxic gases at a pH of between 2 and 12.5
:-reactivity
A waste exhibits the characteristic of toxicity if using the Toxicity Characteristic Leaching Procedure (TCLP), the extract from a representative sample of the waste contains any of the contaminants listed at the concentration equal to or greater than the respective value given in the attached table 1 in blackboard content
:-Toxicity
Identification of hazardous waste (MWAN, KSA)
A waste is hazardous if:
- It is included in the Hazardous Waste List (attached in blackboard)
- It contains one of the hazardous listed constituents (attached in blackboard)
- It displays one of the hazardous properties
- The waste is a mix of hazardous and nonhazardous materials
This involves collection, transportation, storage and disposal of hazardous wastes in an environmentally sound manner, such as landfill designed for hazardous waste
Hazardous Waste Management
It includes:
-Generation
-Transportation
-Storage
-Treatment and final disposal
The Manifest “Cradle to Grave” Hazardous Waste Tracking document links together
Manifest Tracking Document
Hazardous Waste Generator,
Transporters,
Storage facilities,
Treatment plants,
Disposal sites,
Regulatory body
Determination whether wastes are hazardous or Non-hazardous
Label with the word “hazardous waste” on the container used for collection
Mark accumulation start date on the container used for storage of hazardous waste
When it becomes full, containers must be moved to storage area within three days
Inspect the storage tanks
Training the responsible staff
Use the permitted transporter for off-site shipment to permitted disposable facilities.
Responsibilities of hazardous waste generator
Must be in good condition and clean
Must always be closed, except when wastes are added or removed.
Compatibility of the waste with the container (i.e.,
corrosive wastes should not be stored in metal containers) must be ensured.
Waste containers must be filled to not more than 90 percent of the rated capacity of the container.
Containers holding ignitable or reactive waste must be located at least 15 m from the facility property line
Storage container
is any method, technique, or process designed
to physically, chemically, or biologically change the nature of a hazardous waste
Treatment
HAZARDOUS WASTE TREATMENT METHODS:
Activated Carbon Adsorption
Neutralization
Precipitation
Oxidation and Reduction
Biological Treatment
Thermal Treatment (incineration)
-is the attachment of hazardous
constituents in aqueous solutions onto the
surface of adsorbent
-The carbon is highly porous materials with
large surface area
Activated Carbon Adsorption
Organic and metals substances may be
removed from aqueous or gaseous waste
streams by adsorption of the chemical
substances onto activated carbon
Activated Carbon Adsorption