L.5 Balancing Equations Flashcards
OIL RIG
OXIDATION IS LOSS OF ELECTRONS
REDUCTION IS GAIN OF ELECTRONS
Definition of…
Oxidizing agent
Reducing agent
Oxidizing agent = reduced itself, commonly have oxygen or other similar electronegative elements.
Reducing agent = oxidized itself, often contain metal ions or hydrides.
Four steps to assigning oxidation numbers
- Atoms in elemental state = 0
- Atoms in monotonic (exactly one atom Cl-) = oxidation # equal to their charge
3.
F = -1
H = +1 (paired w/less electronegative element = -1)
0 = -2 (unless in peroxide or more electronegative atom = -1)
- Assign oxidation numbers to the rest of the atoms
OTHER STEPS TO REMEMBER
Group 1 = +1
Group 2 = +2
Group 17 = -1 (unless combined with stronger ectronegative element) Group 16 = -2
Group 15 = -3
8 Rules for balancing REDOX Reactions
- write 1/2 rxns
- balance atoms other than oxygen and hydrogen
- balance oxygen by adding h2o
- balance hydrogens by adding H+
- balance charges by adding electrons
- make # of electrons equal ll for 1/2 reactions
- add 1/2 reactions and cancel
- in basic solution add OH to balance H+
Definition of complete ionic equation
Equations that accounts for all of the ions present in a reaction, you have to split all aqueous compounds into their relevant ions, keeping solids intact.
Definition of Net Ionic Equations
An Equation that has only ions that participate in the reactions, eliminate spectator ions
Decomposition Rxn
(NH4)2Cr2O7 –> N2 + Cr2O3 + 4 H2O
Reactant Decomposes AB —–> A + B
Hydrolysis of water = 2 H2O –> O2 + 2H2
-3. +1. +6. -2 0. +3. -2 +1 -2
(NH4)2Cr2O7 –> N2 + Cr2O3 + 4 H2O
Combustion Reaction
CH4 + 2O2 —–> CO2 + 2H2O
A fuel (usually a hydrocarbon ) mixed w/oxidant (usually oxygen) to form carbon dioxide and water.
-4 +1. 0 +4 -2 +1. -2
CH4 + 2O2 —–> CO2 + 2H2O
Combination Reaction
H 2 + F2 ——-> 2HF
- 0 +1. -1
H 2 + F2 ——-> 2HF
Disproportionation Reaction
2H2O2 —–> 2H2O. + O2
A redox reaction in which one element is both oxidized and reduced
+1 -1 +1. -2 0
2H2O2 —–> 2H2O. + O2
Single and Double Displacement
Single = AB + C —–> AC + B
Double = AB + CD —–> AC + BD
Oxidizing Agents
O2 oxygen
H2O2 hydrogen peroxide
Halogens F2 Cl2 Br2 I2
H2SO4 dihydrogen sulfate or sulfuric acid
HNO3 hydrogen nitrate or nitric acid
NaClO sodium hypoclorite
KMnO4 Potassium permanganate
CrO3 Chromium Trioxide
Na2Cr2O7 Sodium Dichromate
PCC (PyridiniumChloromate)
NAD+ and FADH
Reducing Agents
CO Carbon Monoxide
C Carbon
B2H6 Diborane
Sn2+ and other pure metals
Hydrazine (N2H4)
Zn(Hg)
Lindlar’s Catalyst
NaBH4 sodium borohydride
LiAlH4 Lithium aluminohydride
NADH and FADH2
Nomenclature of Ionic Compounds
For elements (usually metals) that can form more than 1 positive ion
Fe2+ Iron II
Fe3+ Iron III
Cu+ Copper I
Cu+2 Copper II
Nomenclature of Ionic Compounds
Ending in -ous or -ic
Fe2+ Ferrous
Fe3+ Ferric
Cu+ Cuprous
Cu2+ Cupric