L16 Adhesives And Adhesion To Tooth Tissue Flashcards
Why do we need adhesion?
Conservation of tooth structure (no undercuts needed for retention)
Reduce post-operative sensitivity
Reduce marginal leakage (marginal seal prevents bacterial invasion)
Many restorations are only possible with adhesion
Which restorations are only possible with adhesion?
Orthodontic brackets, incisal tip restoration, veneers
Pg93 image. What are the critical interfaces when adhering a composite to tooth structure?
Interface a - between adhesive and the enamel/dentine
Interface b - between the adhesive and resin composite
Which interface presents more problems and why?
Interface a due to the dissimilarities in material chemistry’s that we are trying to stick together.
Not as much issue with interface b since bonding adhesive and resin composite are both resin based.
What has a higher chance of achieving good bond strength at an interface?
Similar surface chemistries have a higher chance of achieving bond strength at the interface.
What is the main problem with bonding resin to enamel and dentine?
Enamel and dentine are largely hydrophilic and the resin system is largely hydrophobic. And we don’t want resin-based composite to absorb water or it will break down.
What is in the adhesive to try and resolve the problem?
There is a solvent within the adhesive to help penetrate into surface irregularities in enamel and dentine to help displace water. Try to make them more hydrophilic or less hydrophobic.
What are the factors for ideal bonding?
Clean adherent
Enhanced wettability
Intimate adaptation
Bonding - specific to dental application
Good curing - specific to dental application
Why is a clean adherent needed for ideal bonding?
Rinse mouth out before procedure to rid contaminants.
Etch cleans the surface.
What is wettability?
How well the material adapts to the surface.
What factors enhance wettability for ideal bonding?
Contact angle of adhesive on enamel/dentine
Viscosity contributing to it spreading
Making it more hydrophilic (by adding more water soluble resin), or try making the surface less moisture contaminated
What is intimate adaptation?
Manipulating/modifying the surface you are trying to stick to
How does intimate adaption affect ideal bonding?
E.g., etch roughens the surface and increases the surface area
How can bonding factors be used to create ideal bonding?
Bonds with dental adhesives are primarily mechanical - retentive interlocking (like Velcro)
Physical bonds - electrostatic attraction
Chemical bonds - chelation to tooth surface
How can good curing cause ideal bonding?
Light activated. Adhesives are infilled and thin so good curing is easy to optimise.
Is the bonding predictable or unpredictable when bonding resin composites to enamel?
Predictable bonding due to homogenous structure of enamel with inorganic content and high surface energy.
How is the surface of enamel modified and why is it predictable bonding?
Modified by etch to condition the surface, attacking different areas of the crystalline structure. Can attack periphery of prisms and within them, providing a surface amenable to high wetting of liquid being put on there. Thus more predictable than bonding to dentine.