kinetics and equilibrium Flashcards

1
Q

what does kinetics study

A

the rates of chemical reactions

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2
Q

what must particles do to react

A

collide

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3
Q

effective reaction leads to a

A

reaction

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4
Q

ineffective reaction leads to

A

no reactions

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5
Q

what conditions must be met to have an effective collision

A

particles collide with enough energy and particles must have proper orientation

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6
Q

if particles must collide to react, then more collisions equal

A

faster reaction rate

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7
Q

increased temperature in a reaction causes

A

increased average kinetic energy = particles move faster

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8
Q

increased concentration in reactions mean

A

more molecules present in the same amount of space

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9
Q

increased pressure in reactions causes

A

gas molecules to become closer together

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10
Q

what 4 conditions lead to a fast reaction rate

A

increased temperature, increased concentration, increased surface area, increased pressure

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11
Q

when bonds are broken energy is

A

absorbed

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12
Q

when bonds are formed energy is

A

released

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13
Q

what do chemical bonds contain

A

potential chemical energy

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14
Q

what is heat of reaction formula

A

Hproducts - Hreactants

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15
Q

exothermic equals

A

release energy

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16
Q

endothermic equals

A

absorb energy

17
Q

what does a catalyst do

A

speeds up the rate of reaction but doesn’t affect the number of collisions

18
Q

a catalyst provides

A

alternate pathway for a reaction with a lower activation energy

19
Q

enthalpy is

A

energy

20
Q

entropy is

A

randomness or disorder

21
Q

when does enotropy increase

A

when gas is formed and when molecules break apart

22
Q

what do systems in nature favor

A

low enthalpy and high entropy

23
Q

what is equilibrium

A

when the rate of the forward reaction equals the rate of the reverse reaction

24
Q

what are the three types of equilibrium

A

phase, solutions, chemical

25
Q

when is a solution at equilibrium

A

when its saturated

26
Q

what is phase equilibrium

A

rate of one phase changing to another and back is the same

27
Q

what Is chemical equilibrium

A

when rate of forward reaction is equal to the rate of the reverse reaction

28
Q

reactions that are at equilibrium will stay at equilibrium unless

A

a stress causes the equilibrium to shift

29
Q

what will concentrations change do

A

shift in the direction that relieves the stress

30
Q

what does temperature change do

A

increased rate of all reactions

31
Q

increased temperature favors

A

endothermic

32
Q

decreased temperature favors

A

exothermic

33
Q

what does pressure change do

A

increased in pressure favors the side with less gas moles