kinetics Flashcards
what is meant by the collision theory
a reaction can only occur when particles collide with enough sufficient energy to break bonds with the correct orientation
define rate of reaction
change in concentration of reactants per unit of time
define activation energy
minimum amount of energy needed for a reaction to occur
what does the maxwell boltzman distribution curve show
distribution of kinetic energy of molecules in a gas or liquid at a given temp
what is the area under a maxwell boltzman distribution curve
number of particles
how does increase in temp imact a maxwell boltzman curve
increase in temp, Ke increases, more particles have enough Ea, more successful collisions, graph shifts to the right
how does decrease in temp impact a maxwell boltzman graph
decrease in temp, Ke decreases, less particles have enough Ea, less successful collisions, graph shifts to the left
how does concentration affect the rate of reaction
higher number of particles in a given volume, more frequent and successful collisions
how does a catalyst work
they lower the Ea by providing an alternative route without being used up
how does surface area impact rate of reaction
more points of contact for the particles to collide, more frequent and successful collisions.