Kinetics Flashcards
Requirements for a reaction to occur
- collision
- sufficient energy
- correct orientation
Effect of increased surface area (smaller solid size) on rate of reaction
- more solid reactant is exposed
- more collisions can occur at once
- rate of reaction increases
Effect of temperature increase on rate of reaction
- particles move around more quickly
- more collisions occur
- particles have higher energy
- more collisions result in reaction
- rate of reaction increases
Effect of increased pressure on rate of reaction
- more collisions occur with the gas reactant
- rate of reaction increases
Effect of increased concentration on rate of reaction
- more aqueous reactant per unit volume
- more collisions occur
- rate of reaction increases
Effect of temperature increase on a boltzmann distribution
- area under the curve stays the same
- peak moves down to the right
- more particles are above reaction energy
How a catalyst increases rate of reaction
- provides alternative reaction path with lower activation energy
- more collisions result in reaction
- rate of reaction increases
Economic advantages of catalysts
- increased rate of reaction so greater yield of products
- reactions can occur at lower temperature, so lower energy costs and equipment requirements
Why are solid catalysts used for gas reactions
Gas molecules are adsorbed onto the solid, making them more likely to collide and react
Effect of a catalyst on a boltzmann distribution
- shape of the curve stays the same
- activation energy is lower
- more particles have enough energy to react