Kinetic Theory 3.3 Flashcards
Ideal Gas Laws of Boyle and Charles: (Formula)
p X v / T
State dalton’s law?
The pressure of mixtures of gasses is equal to the sum of the pressures of the individual gas components.
Brownians Motion?
the random motion of smoke particles in a gas.
Graham’s Law?
rate of diffusion of a gas is inversely proportional to the square root of the molecular mass.
If a beam of positive ions is injected at right angles into a magnetic field what path do they follow?
They follow a circular path.
for a graph showing force against separation what is true?
- r < @ there is an infinite repulsion.
- The attractive force has a short range.
define mole?
amount of a substance which contains as many basic entries
Avogadro constant
6.022 x 10^23
define molar mass?
mass of one mol
formula for molar volume:
molar volume = molar mass / density
define unified atomic mass unit:
is 1/12 th of the mass of a isolated carbon 1 atom
at constant temperature:
(investigating relationship between pressure, temperature and volume)
p directly proportional to 1 over V
at constant pressure:
V directly proportional to T
at constant volume:
P directly proportional to temperature.
equation for an ideal Gas:
pV = nRT
pressure, volume, no. of moles, molar gas constant, temprature
Molar Gas Constant R
8.31 J mol K
Define ideal gas.
gas which strictly obeys pv=nrt
equation for molar mass?
Molar mass = Mass / Moles
convert from kelvin to celsius :
-273.15
What is the kinetic energy link with temperature for molecule.
greater the temperature is the more kinetic energy is in the molecules.
define elastic collisions.
no loss in kinetic energy.
First assumption of molecules:
volumes of the molecules is a negligible fraction of the volume occupied by the gas.
Second assumption of molecules:
molecules exert negligible forces on one another except during collisions.
Third assumption of molecules:
effect of gravity is negligible
bar ratio with pascal
1 bar = 10^5 Pascals
bar ratio with atmosphere
1 atm = 1.01325 bar
formula that links mean velocity and pressure.
pV = 1/3 Nmc^2
pressure
Volume
mean velocity
mass
Number of molecules
difference between mean speed and mean velocity.
with speed direction is not significant.
root mean square speed :
Crms = root(mean square speed)
mean kinetic energy:
E = 1/2 mc^2
(Crms)
another formula for kinetic energy:
E = 3/2 p V
Mean K.E per molecule:
3/2 K T
we can write kinetic energy with temperature.
E = 3/2 n RT
define molar heat capacity?
heat required to raise the temperature of 1 mol of the gas by 1 K without changing the volume.
Boltzmann constant (K)
1.38 x 10^-23 JK
ideal gas assumes?
- no forces between molecules except during collisions.
- energy of a gas is kinetic and dependant only on temperature.
equation for ideal gas for two systems?
pv/t = pv/t
assumptions for kinetic theory of a gas.
- molecules of a particular gas are the same.
- collisions between molecules and the side of the box are perfectly elastic.
- no force on molecule except during collisions.
- molecules motion is random