Ketones/Aldehydes General Flashcards

1
Q

Base Catalyzed Hydration

What is the product?

A

Geminal diol + -OH

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2
Q

Base Catalyzed Hydration

What attacks the carbonyl carbon?

What protonates the O-?

A

-OH attacks carbon

H2O protonates the O-

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3
Q

Acid Catalyzed Hydration

What is the first step?

What attacks the carbonyl carbon?

What deprotonates the H2O?

A

Activate (protonate) the C=O with H3O+

H2O attacks carbonyl carbon

H2O, regenerates H3O+

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4
Q

Base Catalyzed Addition of Alcohols

Acetal / Hemiacetal?

A

Hemiacetal

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5
Q

Base Catalyzed Addition of Alcohols

Match conjugate pair example

A

NaOMe / MeOH

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6
Q

Acid Catalyzed Addition of Alcohols

Acetal/Hemiacetal?

A

Acetal

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