Isomers Flashcards
What are the 2 classes of isomer?
Structural/Constitutional & Geometric
What are structural/constitutional isomers?
Isomers that have the same molecular formula (same number and type of atoms), but a different arrangement/bondings of atoms
What are the 3 different types of structural/constitutional isomers?
positional, branched chain & functional group isomers
What are positional isomers?
Structural isomers where the position of the functional group on the main chain is different
What are branched chain isomers?
Structural isomers where the main carbon chain is a different length due to the formation of side chains
What are functional group isomers?
Structural isomers where the same number and type of atoms are arranged so that different functional groups can form
What are geometric isomers?
Molecules with the same molecular and structural formula but a different arrangement of functional groups around a double bond
Why do alkenes form geometric isomers?
because the double bond is fixed and prevents rotation
What are the 2 forms of a geometric isomer?
cis, trans
What are the 3 requirements for geometric isomerism?
1.) double bond to prevent rotation
2.) Each carbon attached to the double bond must have 2 different groups bonded to it
3.) There must be a common group on each side of the double bond