isomerism Flashcards
what are the main types of isomerism
stereoisomerism and structural isomerism
what different types of structural isomerism
chain isomerism, postional isomerism and functuntional group isomerism
describe chain isomerism
they have changed carbon chains. For example, one might be pentane, the other 2-methylbutane.
or, two or more compounds with similar chemical formulas but distinct carbon atom arrangements in straight or branched chains
describe positional isomerism
The carbon chain is identical, but the functional group is on a different carbon.
describe functional group isomerism
These have the same atoms, but they’re arranged into a different functional group.
e.g propanal and propanone
so when compounds that have the same chemical formula but havedifferent functional groups attached to them
what is stereoisomerism
Stereoisomers are structures with same structural formula but different spatial arrangement of atoms
what rules must apply for E / Z isomers
when there is a restricted rotation of the C=C bond. and if the groups bonded to each carbon atom in the C=C bond are different
what is an E isomer. (trans)
In an E isomer, the two highest priority groups on each carbon atom are on opposite sides of the double bond.
trans - transgender on both teams that dont like them,
what is a Z isomer (cis)
In a Z isomer, the two highest priority groups on each carbon atom are on the same side of the double bond.
how to determine the highest priority group in E/Z isomers
calculate the highest atomic number