isomerism Flashcards

1
Q

what are the main types of isomerism

A

stereoisomerism and structural isomerism

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2
Q

what different types of structural isomerism

A

chain isomerism, postional isomerism and functuntional group isomerism

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3
Q

describe chain isomerism

A

they have changed carbon chains. For example, one might be pentane, the other 2-methylbutane.
or, two or more compounds with similar chemical formulas but distinct carbon atom arrangements in straight or branched chains

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4
Q

describe positional isomerism

A

The carbon chain is identical, but the functional group is on a different carbon.

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5
Q

describe functional group isomerism

A

These have the same atoms, but they’re arranged into a different functional group.
e.g propanal and propanone
so when compounds that have the same chemical formula but havedifferent functional groups attached to them

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6
Q

what is stereoisomerism

A

Stereoisomers are structures with same structural formula but different spatial arrangement of atoms

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7
Q

what rules must apply for E / Z isomers

A

when there is a restricted rotation of the C=C bond. and if the groups bonded to each carbon atom in the C=C bond are different

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8
Q

what is an E isomer. (trans)

A

In an E isomer, the two highest priority groups on each carbon atom are on opposite sides of the double bond.

trans - transgender on both teams that dont like them,

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9
Q

what is a Z isomer (cis)

A

In a Z isomer, the two highest priority groups on each carbon atom are on the same side of the double bond.

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10
Q

how to determine the highest priority group in E/Z isomers

A

calculate the highest atomic number

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