Ionic Product of Water Flashcards

1
Q

What is the dissociation of water?

A

when one water molecule acting as an acid and another molecule acting as a base form a conjugate acid and conjugate base

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2
Q

What is the equation for the ionic product of water?

A

Kw=[H₃O⁺][OH⁻]

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3
Q

What is the value of the ionic product of water?

A

Kw=1x10⁻¹⁴

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4
Q

What is the pH scale?

A

a measure of the concentration of hydrogen ions in the solution

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5
Q

How can the pH of an aqueous solution be calculated?

A

pH=-log[H]

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6
Q

What can be said about the concentration of hydrogen and hydroxide ions in pure water?

A

they are equal

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7
Q

What is an acid?

A

any substance capable of donating a proton

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8
Q

What is a base?

A

any substance capable of accepting a proton

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9
Q

What can be said about water molecules?

A

water is amphoteric-it can act as an acid or a base

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10
Q

What is Ka?

A

a measure of the strength of an acid

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11
Q

What are examples of strong acids?

A
  • hydrochloric acid
  • sulfuric acid
  • nitric acid
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12
Q

What are examples of weak acids?

A
  • ethanoic acid
  • carbonic acid
  • sulphurous acid
  • ALL CARBOXYLIC ACIDS
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13
Q

Strong acid

A

ka>1

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14
Q

Weak acid

A

ka<1

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15
Q

How can the pka of a solution be expressed?

A

pka=-logka

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16
Q

What can be said about a strong acid?

A

a strong acid will have a high ka and a low pka

17
Q

What will a weak acid have?

A

a low ka value and a high pka value

18
Q

What are examples of strong bases?

A

metal hydroxides

19
Q

What are examples of weak bases?

A
  • ammonia

* ammines

20
Q

What is a buffer solution?

A

one in which the pH remains constant when small amounts of acid or base is added

21
Q

What is the pH of an acidic buffer?

A

<7

22
Q

What is an acidic buffer made from?

A

a weak base and one of its salts

23
Q

What is the pH of a basic buffer?

A

> 7

24
Q

What is a basic buffer made from?

A

a weak base and one of its salts

25
Q

What are indicators?

A

dyes that are sensitive to pH

26
Q

What can indicators be used to determine?

A

the end-point in an acid-alkali titration

27
Q

When is the colour change distinguishable using an indicator?

A

when [HIn] and [In] differ by a factor of 10

28
Q

What is the equivalence point?

A

where the graph is almost vertical

29
Q

How does a basic buffer work?

A

when an alkali is added, the large reserve of the ammonium chloride ions combine with the OH ions to form ammonia
when an acid is added the ammonia will dissociate to provide OH ions which combine with the H ions to form water

30
Q

How do acidic buffers work?

A

when an alkali is added the weak acid dissociates to provide hydrogen ions which trap the added hydroxide ions and convert it to water
when an acid is added the large reserve of the ion will trap the added hydrogen and convert them back to the molecular form