Ionic Bonding Flashcards

1
Q

Definition of ionic bonding

A

efa between oppositely charged ions in a giant ionic lattice

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2
Q

Magnitude of LE

A

LE ∝ charge/radius

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3
Q

4 properties of ionic compounds

A
  1. High MP and BP
    - a large ant of energy is req’ed to overcome the strong efa bt oppositely charged ions in a giant ionic lattice
  2. Non-electrical conductor in solid, conductor in molten and aq
    - ions fixed
    - broken down to form mobile ions
  3. Hard but brittle
    -ions arranged in orderly lattice of layered ions, displace one layer of ions relative to another
    -> ions of similar charge to come tgt
    => repulsion fall apart
  4. Soluble in water and polar solvents; insoluble in non-polar
    - ion-dipole interacts release sufficient energy to overcome the large amt of energy to dissociate the interactions bt ionic lattice
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4
Q

Two exceptions of metal + non-metal that give covalent compound?

A

AlCl3

NH4Cl

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5
Q

Why us Na2O fully ionic?

A

It has either a high charge density nor a large polarisable electron cloud
-> orbitals would not overlap
=> ionic

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