Covalent Bonding Flashcards
Define covalent bond
efa bt shared pairs of electrons and positively charge nuclei
How is covalent bond form?
A pair of electrons is shared by two overlapping atomic orbitals
What are two types of covalent bonds?
- Sigma bond
2. Pi bond
Explain sigma bond
Single region of orbital overlap that is formed by head-on overlap of two orbitals of two atoms. The overlap can be between ss, sp and pp orbitals.
Explain pi bond
Two separate regions of overlap that is formed when the p orbital of and atom form a sideways overlap with another p orbital of another atom
What are the 2 requirements to form dative bonds?
- One of the atoms has a lone pair of electrons
2. Another atom had an empty orbital
What are the two factors affecting the strength of covalent bonds?
- Multiple bonds (bond order)
- overlap increases, electron density binding the bonding atoms increase
=> triple>double>single
- no of bond I increases, bond energy increases, bond length decreases - Effectiveness of orbital overlaps
-orbitals used in bonding increases, electron more diffused
- effectiveness of overlap bt atomic orbitals decease
=> bond energy decreases