Ion colours Flashcards

1
Q

Cu2+ (aq)

A

pale blue solution

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2
Q

Cr3+

A

violet solution

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3
Q

Fe2+

A

pale green solution

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4
Q

Fe3+

A

yellow solution

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5
Q

Mn2+

A

pale pink solution

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6
Q

Cu2+ in OH-/NH3

A
  • pale blue PPT
  • [Cu(OH)2(H2O)4]
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7
Q

Cr3+ in OH-/NH3

A
  • dark green PPT
  • [Cr(OH)3(H2O)3]
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8
Q

Fe2+ in OH-/NH3

A
  • Dark green PPT
  • [Fe(OH)2(H2O)4]
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9
Q

Fe3+ in OH-/NH3

A
  • orange-brown PPT
  • [Fe(OH)3(H2O)3]
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10
Q

Mn2+ in OH-/NH3

A
  • pale brown PPT
  • [Mn(OH)2(H2O)4]
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11
Q

What are the 2 transition metals that change colour in excess NH3?

A
  • Cu2+ is dark blue solution [Cu(NH3)4(H2O)2]2+
  • Cr3+ is a purple solution [Cu(NH3)6]3+
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12
Q

What is the only transition metal that changes colour in excess OH-?

A

Cr3+ becomes dark green solution [Cr(OH)6]3-

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13
Q

excess HCl + Cu2+

A

CuCl4 2-
yellow solution

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14
Q

Cu2+/ Cu

A
  • disproportionation of Cu2+ forms brown solid (Cu) and blue solution (CuSO4)
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15
Q

CoCl2.6H2O + excess HCl

A

CoCl4 2-

blue

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16
Q

Cr2O7 2-

A
  • from K2Cr2O7 in 0.1 dm3- H2SO4
  • orange
17
Q

CrO4 2-

A
  • oxidation of Cr3+ w/ hot alkaline hydrogen peroxide
  • yellow
18
Q

MnO4-/Fe2+ to Mn2+/Fe3+ titration

A

-purple MnO4- to pale pink Mn2+

19
Q

I-/ Fe3+ to I2/ Fe 2+ titration

A

orange brown Fe3+ to brown I2