introduction to transition metals Flashcards

1
Q

why are Sc - Zn categorised as d block elements?

A

they have their highest energy electrons in a d sub shell/orbital

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2
Q

give 3 typical properties of d block elements

A
  • high mp/bp
  • shiny
  • good conductors of heat & electricity
  • malleable
  • ductile
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3
Q

what are common uses of iron?

A
  • construction
  • tool production
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4
Q

what are common uses of copper?

A
  • electrical cables
  • water pipes
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5
Q

what are common uses of titanium?

A
  • aerospace industry
  • medical applications such as joint replacements
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6
Q

why do copper and chromium not follow the normal pattern of filling 4s before 3d?

A

a half filled d5 sub shell and full d10 sub shell give additional stability to the atoms

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7
Q

which electrons are lost first when d block elements form ions?

A

4s

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8
Q

define ‘transition metal’

A

a d block element which forms at least 1 ion with a partially filled d sub shell

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9
Q

why are Sc and Zn not transition metals?

A

Sc only forms 3+ ion which has an empty d subshell
Zn only forms 2+ ion which has a full d subshell
- transition elements must have a partially filled d sub shell

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10
Q

state the 3 properties of transition metals that other metals do not have?

A
  • variable oxidation states
  • coloured compounds
  • compounds and elements can act as catalysts
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11
Q

what colour is potassium dichromate?

A

bright orange

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12
Q

what colour is cobalt II chloride?

A

purple pink

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13
Q

what colour is nickel II sulphate?

A

green

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14
Q

what does colour of transition element compounds vary with?

A

oxidation number

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15
Q

what is the catalyst in the Haber process?

A

Fe

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16
Q

what is the catalyst in the contact process?

A

V2O5

17
Q

what is the catalyst in catalytic decomposition of hydrogen peroxide?

A

MnO2

18
Q

what is a homogenous catalyst?

A

catalyst and reactants are in same physical state

19
Q

what is a heterogenous catalyst?

A

catalyst is in different physical state to reactants

20
Q

why do Zn compounds dissolve to form a colourless solution?

A
  • colour is associated with presence of a partially filled d orbital
  • Zn only forms Zn2+ ions
  • Zn2+ ions have a full d sub shell