Introduction to organic chemistry Flashcards

1
Q

Define general formula.

A

An algebraic formula that can be applied to chemicals in the same family.

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2
Q

What is the general formula for alkanes?

A

CnH2n+2

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3
Q

What is the general formula for alkenes?

A

CnH2n

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4
Q

What is the general formula for alcohols?

A

CnH2n+1OH

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5
Q

Define molecular formula.

A

The actual number of atoms in an element/molecule.

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6
Q

Define empirical formula.

A

The simplest whole number ratio of atoms in a compound.

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7
Q

Define structural formula.

A

The arrangement of atoms in a molecule, not showing the bonds.

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8
Q

Define skeletal formula.

A

Shows the bonds of the carbon skeleton and functional groups of a molecule.

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9
Q

Define displayed formula.

A

Shows the arrangement of all the bonds and atoms in a molecule.

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10
Q

What are the properties of a homolgous series?

A

*same functional group
*same general formula
*each successive member increases by CH2
*similar chemical properties

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11
Q

What is the difference in stucture of an aldehyde and ketone?

A

Aldehyde has =O on the end.
Ketone has =O in middle.

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12
Q

Define structural isomers.

A

Same molecular formula, different structural formula.

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13
Q

Define chain isomers.

A

Same molecular formula, different arrangement of the carbon skeleton.

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14
Q

Define position isomers.

A

Same molecular formula, different position of the functional group on carbon skeleton.

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15
Q

Define functional group isomers.

A

Same molecular formula, different functional group.

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16
Q

Define stereoisomers.

A

Same structural formula, different arrangment of atoms in 3D space.

17
Q

Why do E-Z isomers arise?

A

There is restricted rotation around the planar carbon-carbon double bond.

18
Q

Which isomer is the Z isomer?

A

The one with the same atoms/groups on the same side of the double bond.

19
Q

Which isomer is the E isomer?

A

The one with the same atoms/groups on opposite sides of the double bond.