Introduction Flashcards

1
Q

What is the meaning of Thermodynamics?

A

Heat in motion

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2
Q

Universe is made up of?

A

System + Surrounding

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3
Q

What is system?

A

1)Part under investigation
2) small part, interested part

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4
Q

What is surrounding ?

A

Everything except system

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5
Q

Boundary can be of how many types?

A

1)
a) Rigid
b) Flexible
2)
a) Real
b) Imaginary
3)
a) Diathermic
b) Adiabatic

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6
Q

What is Diathermic boundary?

A

Boundary through which heat can flow easily

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7
Q

What is Adiabatic boundary?

A

Boundary through which heat cannot flow
∆q=0

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8
Q

How many types of system are there and what are they?

A

1) Open system
2) Closed system
3) Isolated system

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9
Q

What is open system?

A

Such a system where MASS exchange as well as ENERGY exchange takes place

It has IMAGINARY boundary

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10
Q

How energy exchange takes place?

A

By
1)Heat
Or
2) Work

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11
Q

What us closed system?

A

Such a system where only ENERGY takes place

NO mass exchange
( In a closed vessel)

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12
Q

What is Isolated system?

A

Such a system where no mass exchange as well as no energy exchange takes place

It has Adiabatic ( insulating) boundary

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13
Q

Extensive Property?

A

Depends upon
1) Amount of matter
2) Size of sample

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14
Q

Examples of Extensive?

A

1) Mass
2) Volume
3) No of moles
4) Heat Capacity
5) Energy - Heat , Work
6) Enthalpy
7) Entropy
8) Gibb’s Free Energy
9) Internal Energy

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15
Q

Intensive properties meaning?

A

Does not depend upon
Size of sample or amount of matter

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16
Q

Intensive Properties examples?

A

1) Density
2) Reflective Index
3) Specific Heat Capacity
4) Temperature
5) Pressure
6) Concentration
7) Molarity
8) Molality
9) Mole Fraction
10) Normality
11) Molar Entropy/ Enthalpy
( Entropy=Energy)
12) pH

17
Q

Extensive/Extensive=?

A

Intensive

( X/Y= Z)

18
Q

Formula of Electromotive force?

A

E.F =Work/ Heat
(W/Q)

19
Q

State Variables/ State Functions/ State parameters meaning?

A

Variables which define the state or condition of system

State Functions depends upon only INITIAL and FINAL state

eg- PRESSURE, VOLUME, TEMPERATURE of gas

20
Q

State Variables examples?

A

1) Pressure
2) Temperature
3) Volume
4) no of moles ( n)
5) Enthalpy (H)
6) Entropy (S)
7) Internal Energy ( E/U)
8) Gibb’s Free Energy ( G)

21
Q

Heat and Work are state Functions .
Is it true?

A

NO, not true
Heat & Work are PATH function

22
Q

What is the value of change in state Functions in any cyclic process?

A

ZERO
Because state functions depends upon initial & final state and in cyclic they are the same