Intro to organic chemistry Flashcards

1
Q

what is a hydrocarbon

A

a compound containing only hydrogen and carbon

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2
Q

what is saturated

A

only has single carbon carbon bonds

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3
Q

what is unsaturated

A

contains double carbon carbon bonds

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4
Q

what is the molecular formula

A

shows the number of each type of atom

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5
Q

what is the empirical formula

A

shows the simplest whole number ratio of atoms of each element in a compound

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6
Q

structural formula

A

shows in minimal detail the arrangement of all the atoms

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7
Q

functional group of an alcohol

A

C-OH bond

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8
Q

functional group of halogenoalkanes

A

C-HALOGEN

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9
Q

functional group of aldehydes

A

O=C-H

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10
Q

functional group of ketones

A

C=O

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11
Q

functional group of carboxylic acids

A

O=C-OH

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12
Q

functional group of esters

A

O=C-O-
suffix -yl-oate

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13
Q

order of priority of functional groups

A

Carboxylic acids
Aldehydes
Ketones
Alcohols
Alkenes
Halogenoalkanes

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14
Q

where is the C=O bonds of an aldehyde always on in a carbon chain

A

always on carbon 1

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15
Q

what is homolytic fission

A

each atom gets one electron from the covalent bond

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16
Q

what is formed when a bond breaks by homolytic fission

A

free radicals

17
Q

what are free radicals

A

a reactive species that have an unpaired electron. They don’t have a charge and are represented by a dot

18
Q

what is heterolytic fission

A

when one atom gets both electrons

19
Q

what kind of arrow shows the movement of one electron

A

one headed arrow

20
Q

what kind of arrow shows the movement of both electrons

A

2 headed arrow

21
Q

what does heterolytic fission produce

22
Q

what are structural isomers

A

same molecular formular but different structures

23
Q

types of structural isomerism

A

chain isomers
position isomers
functional isomers

24
Q

what is a chain isomer

A

same molecular formula but different structures of the carbon skeleton

25
what is a position isomer
same molecular formula but different positions of the same functional group on the same carbon skeleton
26
what is functional group isomers
same molecular formula but atoms rearranged to give different functional groups
27
when do EZ isomers arise
1. when there is restricted rotation around the C=C bond 2. there are 2 different groups attached to both ends of the double bond
28
what will be the priority group when naming EZ isomers
the atom with the higher atomic number has higher priority