Alkenes Flashcards
are alkenes saturated or unsaturated
unsaturated
what is an unsaturated hydrocarbon
containing carbon carbon double bonds
is a pi bond stronger or a sigma bond
sigma bond is stronger
when alkenes react what type of bond breaks first
pi bond
what happens in the addition reaction of an alkene
the pi bond breaks and new atoms or groups are added to for a single product
what is an electrophile
an electron pair acceptor ( attracted to regions of high electron density)
why do alkenes attract electrophiles
they have a C=C which is an area of high electron density
what are the different electrophilic addition reactions that alkenes go through
- reaction with bromine ( and other halogens)
- reaction with hydrogen halides
- reaction with conc sulfuric acid
- reaction with water
reaction with bromine allows us to test for unsaturation in hydrocarbons. What happens when bromine water is added to an alkene
Br2 water is decolourised (goes from and orange brown solution to a colourless solution)
what type of species is formed in the intermediate reaction when an alkene reacts with bromine
carbocation
why does the secondary carbocation form the major product over the primary carbocation
it is more stable due to having more e- releasing alkyl groups
conditions needed for the reaction of alkenes with H2SO4
cold conc H2SO4
conditions needed for the reaction between alkenes and water
H3PO4 catalyst, 70 atm, high temp (300 degrees)
Alkenes + H2O
alcohols
what can alkyl hydrogen sulphates be further reacted with H2O to form
alcohols
how do alkenes undergo polymerisation to form a polymer chain
pi bond breaks and the e- pair is used to form a bond with a C atom on a neighbouring molecule
what type of polymerisation do alkenes undergo
addition polymerisation
what catalyst is required to bring about polymerisation
Zeigler - Natta catalyst
advantages of landfill
easy
quick
cheap
disadvantages of landfill
limited space
not sustainable
eyesore
advantages of incineration
reduced waste
effective disposal
disadvantages of incineration
releases harmful products such as CO2
greenhouse effect
advantages of recylcing
sustainable
conserves natural resources
less waste
disadvantages of recylcing
expensive
time consuming