Alkenes Flashcards

1
Q

are alkenes saturated or unsaturated

A

unsaturated

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2
Q

what is an unsaturated hydrocarbon

A

containing carbon carbon double bonds

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3
Q

is a pi bond stronger or a sigma bond

A

sigma bond is stronger

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4
Q

when alkenes react what type of bond breaks first

A

pi bond

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5
Q

what happens in the addition reaction of an alkene

A

the pi bond breaks and new atoms or groups are added to for a single product

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6
Q

what is an electrophile

A

an electron pair acceptor ( attracted to regions of high electron density)

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7
Q

why do alkenes attract electrophiles

A

they have a C=C which is an area of high electron density

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8
Q

what are the different electrophilic addition reactions that alkenes go through

A
  • reaction with bromine ( and other halogens)
  • reaction with hydrogen halides
  • reaction with conc sulfuric acid
  • reaction with water
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9
Q

reaction with bromine allows us to test for unsaturation in hydrocarbons. What happens when bromine water is added to an alkene

A

Br2 water is decolourised (goes from and orange brown solution to a colourless solution)

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10
Q

what type of species is formed in the intermediate reaction when an alkene reacts with bromine

A

carbocation

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11
Q

why does the secondary carbocation form the major product over the primary carbocation

A

it is more stable due to having more e- releasing alkyl groups

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12
Q

conditions needed for the reaction of alkenes with H2SO4

A

cold conc H2SO4

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13
Q

conditions needed for the reaction between alkenes and water

A

H3PO4 catalyst, 70 atm, high temp (300 degrees)

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14
Q

Alkenes + H2O

A

alcohols

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15
Q

what can alkyl hydrogen sulphates be further reacted with H2O to form

A

alcohols

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16
Q

how do alkenes undergo polymerisation to form a polymer chain

A

pi bond breaks and the e- pair is used to form a bond with a C atom on a neighbouring molecule

17
Q

what type of polymerisation do alkenes undergo

A

addition polymerisation

18
Q

what catalyst is required to bring about polymerisation

A

Zeigler - Natta catalyst

19
Q

advantages of landfill

A

easy
quick
cheap

20
Q

disadvantages of landfill

A

limited space
not sustainable
eyesore

21
Q

advantages of incineration

A

reduced waste
effective disposal

22
Q

disadvantages of incineration

A

releases harmful products such as CO2
greenhouse effect

23
Q

advantages of recylcing

A

sustainable
conserves natural resources
less waste

24
Q

disadvantages of recylcing

A

expensive
time consuming