Intro 6 Flashcards
When any reaction undergoes through kinetic path mens it’s activation energy will
Be less
Substrate aur product ke beech ka distance jitney zada hoga wo utna he
Thermodynamicallly stable product hoga
So deltaG is the factors to which thermodynamic product depend not the activation energy
Kya HOMO NECHE AUR LUMO UPER HOTA HAI HAMESA
Nhi kuch wise bhi case aaate hai jaha ye dono barabar bhi hostel hai ,ur ludo neeche aur homo super bhi ho skta hai
Kya koi ek he product thermo aur kinetic dono favourable ho skta hai
Yes
When bond length if high then the energy of antibodies orbital
Is lower
And when it’s energy is lower bonds can easily breaks because of easily coming of electrons in antibonding
CH,CF,CCL,CBr,CI
Antibonding orbital ki energy sabse low kismet hogi
Sbse low to CI me hogi because of larger bond length
Usually leaving groups jo carbon se attached hote hai koine hote hai ?
Halogens
Oxygen
CH AND CF me kiski bond length zada hai
CF ki to ye bond easily brak ho skta hai
CF and CO me kiski bond length zada hai
CO ki
In Alkene EDG or EWG what will it does
Edg increase electron density means energy of alkene increase [ BMO OR ABMO increase energy]
EwG do opposite [ decrease energy]