EAS Flashcards

1
Q

In electrophilic aromatic substitution

A

First electrophilic aatach with Lewis acid
Electrophile attach with benzene
Benzene remove h+ where electrophile attach itself

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2
Q

Leaving group of how many types

A

3
Negative = cl- ,Br-, l-
Natural gas = co2, so2, n2
Neutral solvent = h2o, roh
Positive = si+me3,h+

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3
Q

Rate determining step

A

When electrophilic added to benzene ring and carbocation is formed

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4
Q

Rate of substitution faster in benzene ring have hydrogen,deuterium, tritium

A

Equal
In case of sulphonation and iodination these are not equal

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5
Q

N2O5 BREAKS IN TO

A

NO3- , NO2+

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6
Q

HNO3 + H2SO4 GIVE NO2 +
HNO3 ACT AS A

A

Base

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7
Q

BF4NO2 and conc. HNO3 GIVE

A

NO2+

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8
Q

Cl2 kya paida karta hai

A

Cl + electrophile

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9
Q

Br–f/ AlCl3=
Cl–I/ AlCl3

A

Br+
I+

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10
Q

RCN+H+ /H2O

A

RC=O

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11
Q

CH2O+HCI

A

Ch2+cl

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12
Q

CO + H+

A

Aldehyde

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13
Q

CLSO2H+ H+

A

ClSO2

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14
Q

In intramolecular EAS 3,4 membered ring not formed

A
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15
Q

Ch3 hee bs ortho major deta hai 2,3 jo hai para major dete hai

A
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16
Q

In intramolecular EAS PARA product not preferred

A

Because bridge head carbon

17
Q

In case of alcohol or epoxide only 6 membered ring preferre

A

Otherwise elimination occur

18
Q

Nitration of phenol major product

A

Ortho

19
Q

In phenol ring why poly nitration not occur but poy bromination take place

A

Nitration ki wajah se benzene ring electron deficient ho jayega

20
Q

P2O5 work

A

Removal of water

21
Q

2:46

A