EAS Flashcards
In electrophilic aromatic substitution
First electrophilic aatach with Lewis acid
Electrophile attach with benzene
Benzene remove h+ where electrophile attach itself
Leaving group of how many types
3
Negative = cl- ,Br-, l-
Natural gas = co2, so2, n2
Neutral solvent = h2o, roh
Positive = si+me3,h+
Rate determining step
When electrophilic added to benzene ring and carbocation is formed
Rate of substitution faster in benzene ring have hydrogen,deuterium, tritium
Equal
In case of sulphonation and iodination these are not equal
N2O5 BREAKS IN TO
NO3- , NO2+
HNO3 + H2SO4 GIVE NO2 +
HNO3 ACT AS A
Base
BF4NO2 and conc. HNO3 GIVE
NO2+
Cl2 kya paida karta hai
Cl + electrophile
Br–f/ AlCl3=
Cl–I/ AlCl3
Br+
I+
RCN+H+ /H2O
RC=O
CH2O+HCI
Ch2+cl
CO + H+
Aldehyde
CLSO2H+ H+
ClSO2
In intramolecular EAS 3,4 membered ring not formed
Ch3 hee bs ortho major deta hai 2,3 jo hai para major dete hai