internal processes Flashcards
what are the five ways in which we can collect informationof the internal earth?
drilling
geophysics
experiments
geochemistry
meteorites
how can geophysics be used to inform us of the internal earth
remote sensing
- seismic
- gravity
- magnetics
- prescence of melt
how does minerology provide information of the intenal earth?
certain minerals provide insight into pressure and temperature conditions
what is the importance of meteroites?
- instrumental in determining the age of the earth
- some meteroites are also believed to be good approximates of the bulk composition of the earth
what are the three types of metorites?
- Stones – consisting largely of silicate minerals (similar to earth rocks)
- Irons – alloys of iron and nickel
- Stoney irons – have roughly equal proportions of iron- nickel and silicate
what is the rarest type of meteorite and why?
stony ones are less common because they look like any other rock and are more susceptible to weathering
define: igneous rock
igneous rock
a rock that has formed by the cooling of a liquid(magma, melt, lava)
define: magma
magma
a completely or partly molten natural substance that on cooling solidifies as a crystalline or glassy igneous rock
define: melt
melt
the liquid part of magma with no crystalline phases or inherited solid
define: lava
lava
a magma that due to volcanic activity is released on to the surface of the earth
define: plutonic rock
plutonic rock
is formed from magma that crystallised beneath the earths surface
what is igneous petrology?
igneous petrology
is the study of igneous rocks. it link mineralogy, geochemistry, field work, and physics
where is the largest magma production rate?
oceanic ridges
where is there greater magma production, volcanic or plutonic?
plutonic
what are the three most common elements in the crust? give general %
O - 46.6%
Si - 27.7%
Al - 8.3%
what are the most common minerals in crustal rocks and why?
Si and O are by far the most common elements thus silicates are the most common minrals in crustal rocks.
what is the building block of silicates?
SiO4 group = tetrahedron
how are silicate tetrahedra used to make minerals?
polymerisation of tetrahedral
we can combine the basic string of silicate tetrahedra together to form templates. how are these templates held together?
templates require cations (usually metals) to balance the charge.
metals are loacted in cavities
which minerals are single, double chain, and sheet silicates?
what three things cause melting?
heat
pressure changes
water
in partial melting is the melt more or less rich in silica than the starting material?
in partial melting the melt is richer in silica than the starting material.
e.g. partial melting of an ultramafic rock will yield a mafic melt.
what is the solidus?
P -T line where melting begins
what is the liquidus?
P - T line where melting is complete
what is anhydrous melting?
melting without water or no hydrous minerals
how is anhydrous melting brought about?
by increase in temperature or decrease in pressue (or both
is the composition of the liquid the same or different to the remaing solid in anhydrous melting?
the composition of the liquid is different to that of the remaining solid
what type of heat transfer is in the lithospher and the asthenosphere?
lithosphere - conduction
convection - asthenosphere
what is adiabatic decompression?
decompression where no heat is lost to the surrounding rock
what is hydrous melting?
melting with water or hydrous minerals
how does the addition of water change the solidus and liquidus?
moves them to the left and negative gradient
where does the anhydrous and hydrous melting curves converge?
anhydrous and hydrous melting converge at low pressure.
what is congruent and incongruent melting and which is more common?
congruent - melt produced has same composition as starting material e.g calcite –> carbonate
incongruent - the opposite
incongruent is the norm
the structure of quartz is entirely bulit from SiO4 units. why then is its chemical formula SiO2?
quartx is created from each tetrahedra being connected to four other tetrahedra. the tetrahedra share corners (e.g. each O atom is shared between two tetrahedra). this makes the ratio of Si to O 1:2 and hance the chemical formula of quartz SiO2
what is a solid solution? give examples of two important rock forming minerals that show solid solutions.
solid solutin refers to the range of chemical compositions possible for a given crystal structure.
solid solution involves the subsitution of one or more atoms or ions at specific sites in the crystal structure.
e.g. olvine can range from pure Mg2SiO4 to pure Fe2SiO4 with a continuos spread of solid solution compositions inbetween.
another example is plagioclase (anorthite to albite) and alkali feldspar (albite - K-spar)
suggest why parial melting of a mafic source rock is nlikely to yield a large body of felsic magma?
the first melt to form during partial metling of a mafic rock will tend to be intermediate in compositon.
however even if the first tiny fration of the melt was felsic, it would be too viscous to flow and thus cant group into large bodies.
as partial melting proceeded, the melt would become progressively less felsic, and the average composition of the melt would certainly be intermediate before enough melt can be collected to be able to rise freely.
what are the four properties of magma?
structure
temperature
viscosity
density
what are the 5 types of magma?
Melt only that generally contains only dissolved volatiles (single phase system)
Melt plus bubbles of volatile fluid (two phase system)
Melt plus crystals (two phase system)
Two immiscible melts of different composition (two phase system) like oil and water
Melt plus bubbles of volatile fluid and crystals of olivine and plagioclase (four phase system)
give examples of volatiles
water
carbon dioxide
what is the effect of changing pressure on volatiles?
changes in pressure cause volatiles to exsolve (undissolve) making gases
what effect does volatiles have rocks?
they break up the silica chains
which do volatiles have a greater effect on, felsic or mafic rocks? and why?
Volatiles have a greater effect on felsic rich as there are silica chains to disrupt.
On mafic rocks it has little effect due to no chains to disrupt.
describe the atomic structure of magma
SiO44- unit covalently bonded = remains as a unit during melting
Other bonds in minerals are weaker – they are the ones that break during melting
More felsic magmas have higher SiO4 = more links = polymerisation (creating links)
Network formers (SiO44-, MAlO44-) (M= metallic ions that keep the charge 4- and keeps the chemical structure) and network modifiers (cations, volatiles)
Felsic magmas have more links and thus remains long chains and has greatest changes.
which is more viscous out of felsic and mafic magmas and has the greatest changes? and why?
More felsic magmas have higher SiO4 = more links = polymerisation (creating links) thus more viscous.
Felsic magmas have more links and thus remains long chains and has greatest changes.
around what is the temperature of erupting magmas?
800oC to 1200oC
how can we use temperature to decide the composition of a magma?
Low temperatures = felsic compositions (rhyolite)
High temperatures = mafic compositions (basalt)
what is viscosity?
it is the Resistance to flow
Long polymerised chains hinder the flow
thus Felsic magmas more viscous than mafic
Volatiles disrupt polymerisation
what are the variables of viscosity?
temperature
time
pressure
how can a plume get blocked as magma raises to the surface? what happens if there is too much pressure?
As magma goes to the surface it lowers pressure thus volatiles exsolve. This increases viscosity and can then block the plume.
Thus an increase in pressure below can cause explosive eruptions.
what happens as lava flows away from their source or vent?
As lavas flow away from their source or vent, they cool and viscosity increases.
Viscosity of a mauna loa flow increased 2 fold over 20Km
Viscosity of a small flow from Mt. Etna increased 375-fold over 500m
why is there a difference?
Mt Etna is more felsic so it is much more viscous.
Thus it depends on the composition and temperature of the magma.
why does viscosity increase as it cools down?
As it cools down it has greater polymerisation so longer, more organised chains, so more viscous.
And the creation of crystals which creates an increase in viscosity.
describe this graph.
Crystals formed over a longer time will be larger thus interfere with melt flow.
If the same temp cooling is over a longer time it will be more viscous as the creation of crystals.
describe this graph
Increase in water content by one order of magnitude decreases viscosity by up to 6 orders.
water has no effect on mafic rocks as there are no silica chains to disrupt
does water have a greater effect on felsic or mafic rocks in terms of viscosity? why?
has a greater effect on felsic rocks as mafic rocks dont have any silica chains to disrupt thus adding water will have no impact,
why is viscosity important?
It affects how magmas are transported
It dictates the eruption style of volcanoes
what are the 7 textures of volcanic rocks?
Extrusive or volcanic rocks - rapid cooling - fine grained (< 0.25 mm)
Intrusive or plutonic rocks - slow cooling - coarse grained (> 2 mm)
Intermediate or hypabyssal rocks (dykes and sills) - medium grained (0.25 – 2 mm)
Volcanic glass or obsidian (fast cooling)
Phaneritic: mineral grains large enough to be identified by eye (> 1 mm)
Aphanitic: grains too small to be identified by eye (< 1 mm)
Porphyritic: two grain size populations (phenocrysts and groundmass) = initial slow cooling stage at depth followed by rapid cooling at or near the surface (can also be due to volatile exsolution which causes crystallisation thus we get or deposits from the volatiles
what is the nucleation centres texture?
Two stage crystallisation
If one mineral nucleates earlier or faster than others it may form large phenocrysts
describe the intergranular texture
Intergranular texture: when crystal nucleate and grow at the same rate.
what is formed when rapid cooling and supersaturation takes place?
Long slender crystals
Crystals that radiate from a common centre
Curved clusters of microlites
Skeletal crystals with hollow cores.
describe the porphyritic texture
Phenocrysts
Important for ore deposits
Eruption or volatile exsolution.
describe cumulate texture
Crystal settling
Layering
Layered intrusions
Coarse equidimensional crystals
Economic importance – lots of platinum.
give the three names to describe cumulate textures.
what do the names depend on?
they depend on the number of small crystals in it produced by the crystallisation of the intercumulus liquid.
left - orthcumulate
middle - mesocumulate
right - adcumulate
describe flow textures
Alignment of crystals in flowing magma
if feldspars are well aligned: trachytic
Glassy rocks may show flow delineated by vesicles parallel to the direction of flow.
how can we work out the order of crystallisation?
If a crystal surrounds another, it is younger
Early formed crystals are commonly euhedral, or at least more so than later formed ones
If larger and smaller crystals of the same mineral coexist, the larger ones began to grow first
BUT…
Interlocking grains that grow simultaneously may appear to cut each other
Included crystals may have crystallised later (e.g. exsolution)
what is the modal classification of felsic and mafic minerals?
Felsic: feldspar and silica = feldspar, feldspathoids, silica (light colour)
Mafic: magnesium and ferrous/ferric (ferromagnesian) = olivine, pyroxene, amphibole, opaques, accessory (dark colour)
what is the colour index?
Colour Index (CI): volume percentage of mafic or dark coloured minerals
for felsic, intermediate, mafic and ultramafic minerals what are the wt% SiO2 boundaries?
felsic > 65
intermediate - 52 - 65
mafic - 45 - 52
ultramafic <45
for felsic, intermediate, mafic and ultramafic minerals what are the colour index boundaries?
felsic 0 -35
intermediate 35 -65
mafic 65 -90
ultramafic 90 - 100
which mineral doesnt form a solid solution?
quartz
olivine cant coexist with?
quartz (as olivine is ultramafic and quartz it felsic)
earliest formed feldspars are _____________ rich
Earliest formed feldspars are calcium rich.
in a QAPF diagram what does QAPF stand for?
Q: quartz (tridymite, cristobalite)
A: alkali feldspars - orthoclase
P: plagioclase
F: feldspathoids or foids
before using a QAPF diagram what must we do?
we must minus the mafic proportion and then recalculate
when cant we use a QAPF diagram?
we cant use it when the grains are too fine
contains no matrix glass
if CI > 90
what are the wt% of major, minor and trace elements?
major elements > 1 wt%
minor elements 0.1 - 1.0 wt%
trace elements < 0.1 wt%
is the mineralogy of a rock dependent or independent of cooling rate?
mineralogy is independent of cooling rate e.g. gabbro, dolerite and basalt all have the same mineals and same composition.
what is a TAS diagram?
it is a classification of aphanitic and glassy volcanic rocks
what does TAS stand for?
TAS = Total Alkalis + Silica
alkalis = Na2O + K2O
as a magma cools what happens to the dense crystals?
as it cools the dense crystals leave the system
describe the Bowens reaction series
bowen suggested that the common minerals that crystallize from magma could be divided into a continuous reaction series and a discontinuous reaction series.
they dont crystallise one after another but instead they gradually change from one mineral to another.
plagioclase crystallises throughout the range however only calcium plagioclase crystallises first then it becomes more sodium rich.
mafic minerals crystallise first then felsic minerals
what is magmatic differentiation?
Differentiation is defined as any process by which magmas evolve and become more diversified
what are the two components of magmatic differentiation?
Two components:
Chemical
Physical
The chemical part establishes compositional differences in one or more phases (crystal growth)
The physical part allows the preservation of these differences by segregating or fractionating the phases so they can form distinctive rocks
the compositions of the rock forming minerals are _______ than the melts from which they form
The compositions of the rock-forming minerals are** simpler** than the melts (liquids) from which they form
the igneous minerals consist of a relatively small number of ____________ most of which have a ________ concentration in the crystal than in the melt
The igneous minerals consist of a relatively small number of essential constituents, most of which have a higher concentration in the crystal than in the melt.
as a crystal grows in the melt, the elements required by the mineral becomes more _________ in the melt
As a crystal grows in a melt, the elements required by the mineral becomes more depleted in the melt
Elements that are not required by the mineral are __________ in the diminishing volume or the residual (remaining) melt – these are termed ___________
Elements that are not required by the mineral are enriched in the diminishing volume or the residual (remaining) melt – these are termed incompatible
If the melt and solid are separated completely the final residual melt will have _________ composition from that at the beginning
Therefore when it finally crystallizes it will produce a rock ____________ composition
If the melt and solid are separated completely the final residual melt will have a very different composition from that at the beginning
Therefore when it finally crystallizes it will produce a rock of a very different composition
what does it mean if the distribution coefficient Kd is less than one?
Kd < 1 means the element is incompatible in the mineral (will be enriched in the melt)
what is the bulk distribution coefficient D?
Bulk distribution coefficient D is the sum of the individual Kd’s for a given element for all the minerals present in a magma:
Di = ∑Kd<span>i</span>xi (X is the percentage of element in mineral)
what is the bulk distribution D used for?
D can be used to model how a trace element changes in concentration in the melt as several minerals crystallize together
in terms of grains where does the melt form?
Melt forms at grain boundaries
how does the melt move around the grains?
Melt “wets” grains resulting in interconnectivity rather than drops
Melt in pockets and pockets connected by channels
Silicate melts are less dense than rocks of same composition
thus Melt less dense than solid so rises due to buoyency
Need 5% melting to overcome viscosity and surface tension
Cracks (dykes) allow magma to rapidly migrate created due to tectonic deformation
what scales do we need for significant migration through the crust?
need km sized bodies (30% melt)
this is due to the loss of heat to surrounding rocks and thus crystallising
give a way in which we can increase buoyancy of a melt?
Separation of crystals from melt + fractional crystallisation = melt becomes more felsic = more buoyant
Problem – mafic magma migration
- Volatile undersaturated basaltic magmas have a density of > 2700 kg/m3
- Continental crust average ~ 2700kg/m3
- Basaltic magmas would not be expected to riseEvidence for appreciable underplating of the lower continental crust
- Quartz- feldspar- rich (crustal) rocks therefore effectively serve as a density filter
So how do basaltic melt ever get to the surface?
If it is saturated in volatiles then its density decreases and thus there is a buoyancy force.
Also tectonic activity can compress the magma and thus moves upwards (like toothpaste)
what is underplating?
underplating
basaltic magma rises and then gets stuck under the continental crust.
what are diapirs?
are bodies of buoyant magma that push slowly through surrounding ductile, highly viscous country rock in the lower crust or mantle
Diapiric rise involves density driven rising of buoyant magma through denser country rock. Its mechanically easier for the magma to penetrate upwards as a thin dike rather than a large blob.
what is meant by assimilation?
Melting and incorporation of the melted wall rock into the magma in the pluton = assimilation
Basaltic magma ~12000C so can melt the rocks.
what is stoping?
At shallow level where country rocks are brittle, thermal and mechanical stresses associated with pluton emplacement can fracture rocks.
Relatively dense, detached blocks can sink into the deeper parts of the magma chamber.
With long exposure to the magma, xenoliths can partially melt and become disaggregated and so gradually lose their identity.
what are xenoliths?
found in igneous rocks
common near roof and walls
plucked from country rock during stoping
recrystallised fabric
partial assimilation can take place
what is meant by plutonic?
plutonic:
igneous rocks emplaced at depth below the surface of the earth
what is meant by hypabyssal?
hypabyssal:
pertaining to rocks whose type of emplacement is intermediate between plutonic and volcanic
often applied to rocks from minor intrusions, e.g. sills and dykes
what are plutons?
intruded magmas that crystallise at depth
coarse grained
exposed as a result of crustal thickening – erosion – isostatic uplift
collision zones, destructive margins
describe deep plutons
Mid-crustal (~20km)
Felsic/intermediate composition
Associated with gneisses and schists
Can form by partial melting of metamorphic rocks
Migmatite
Elongate masses of granite aligned with foliation
Granite foliated = granite gneiss
describe intermediate depth plutons
~10km
Single large pluton
Maybe associated with regional metamorphism
Edges parallel to foliation in country rock
Country rock hot and deformable
Diaper
Solidify in 105 years
describe shallow plutons
<10km
Discordant
Cold, brittle crust
Space created by fractures and faults
Magma moves up structures (cooling to form dykes)
right image
describe how space is made for shallow plutons.
describe a composite pluton
Many plutons are composite, being formed of more than one type of igneous rock. These may represent different batches of magma, or the same magma frozen at different stages of its evolution.
Using cross cutting relationships and radiometric dating allows us to determine the order of formation.
what are batholiths?
Successive pulses of magma
Combination of plutons
>100km2 in surface area
Take a long period of time to form
Batholiths are large, composite plutonic bodies. They can cover tens of thousands of square kilometers and be made of large number of individual plutonic bodies. They form in regions that had large magma supplies for long periods, such as subduction zones or slow continental rifts.
what are laccoliths?
Laccoliths are broadly concordant with sedimentary strata
Blister shaped
Sub- horizontal base
Elevated upper surface
especially thick sills that substantially bulge up their roofs
are usually formed from viscous magma emplaced at shallow depths.
what are lopoliths?
Lopoliths are large, spoon-shaped igneous rock bodies.
Most are mafic and have prominent igneous layering produced by crystal settling.
The largest known lopolith is the Bushveld complex in South Africa, which is 240km x 480km x 8km thick
what is a dyke?
a minor intrusion at shallow depth
Dyke = disconcordant (cut existing structures and strata)Fine or medium grain size
Dykes are tabular, thin intrusive bodies that crosscut layering.
what are sills?
minor intrusions - shallow depth
concordant with strata
Sills are thin, tabular intrusives that generally parallel rock layering.
describe the general shape of the magma chambers below volcanoes
Magma chambers aren’t round ‘blobs’ under volcanoes
Complex architecture = plumbing system
what controls the shape of magma chambers?
controlled by structures in the brittle crust
what are the three types of dyke associated with a volcano?
ring dyke
cone sheet
radiating dykes
what is a volcanic neck?
solidified volcanic conduit of the volcano
its where the volcano edges have been eroded away leaving the column of harder rock behind.
describe the differences between mafic and felsic dykes. why the difference?
mafic - thin, longer dykes due to
where do phenocrysts grow?
phenocrysts grow inside the magma
crystals thus have the same chemical composition as the magma
where do xenocrysts grow?
single crystal xenocryst broken from the dyke walls
different composition to the magma thus isnt the same as the magma.
xeno = foreign
where do xenoliths come from?
xenoliths are polycrystalline and broken from the dykes wall
xeno = foreign
lith = rock
explain why there are differing grain sizes in a dyke
grain size variations caused by differential cooling rates at different distances from the margin.
what margins are associated with dykes?
chilled margins
baked margins
very limited contact metamorphism