intermolecular forces and solids Flashcards

1
Q

Intermolecular forces are____

A

forces that occur between molecules

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2
Q

Intramolecular forces are ______

A

forces that occur in molecules

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3
Q

The strongest intermolecular force is

A

ion-ion force

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4
Q

What intermolecular force binds ions into crystals?

A

ion-ion force

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5
Q

Which is stronger: intermolecular or intramolecular?

A

intramolecular is stronger

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6
Q

What does ion-ion bonding depend on?

A

It depends on the charge and distance. The higher that charge, the stronger the bond, and the larger the distance, the weaker the bond.

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7
Q

What is a dipole?

A

A dipole is a permanent distortion in electron that causes partial charges on different ends or poles of the molecule.

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8
Q

The strength of an ion-dipole is dependent on?

A

The strength of an ion-dipole is dependent on the charge and the radius of the atoms/molecules

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9
Q

heat of hydration

A

the energy it takes to add water to a system

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10
Q

relationship between heat of hydration and strength of ion-dipole

A

the stronger the ion-dipole, the more heat of hydration is present

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11
Q

Dipole-dipole interaction

A

this occurs between a dipole molecule and another dipole. The positive end of one orients itself so that it attracts the negative of the other.

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12
Q

strength of dipole-dipole depends on?

A

the strength depends on the magnitude. The bigger the dipole, the stronger the interaction

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13
Q

Hydrogen bonding

A

a hydrogen bond is a special type of dipole-dipole. This occurs when hydrogen bonds to a very electronegative atom/molecules that take so much of its electron that it is almost a proton.

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14
Q

What electronegative atoms/molecules can hydrogen bond?

A

Fluorine, oxygen, and nitrogen (FON)

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15
Q

Relationship between melting/boiling points with the strength of interaction

A

The stronger the interaction, the higher the boiling or melting point.

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16
Q

Induced dipoles

A

These are temporary dipoles.

17
Q

ion-induced dipole

A

This occurs when an ion approaches a nonpolar substance and causes it to form a temporary dipole

18
Q

dipole-induced dipole

A

This occurs when a dipole approached a nonpolar substance and causes it to form a temporary dipole

19
Q

induced dipole-induced dipole

A

This occurs when an induced dipole approaches a nonpolar substance and causes sit to form a temporary dipole. They are also known as Lizard Dispersion forces

20
Q

Strength of induced dipoles

A

The strength of an induced dipole is dependent on the size of the atom/molecule

21
Q

Arrange the intermolecular forces from strongest to weakest.

A

ion-ion> ion-dipole> hydrogen bonding> dipole-dipole> ion-induced dipole> dipole-induced dipole> induced dipole-induced dipole

22
Q

crystalline solid

A

it is an ordered arrangement of repeated unit cells that have a lattice

23
Q

amorphous solid

A

it is a solid that has no repeated array. It has no lattice

24
Q

unit cell

A

it is the basic repeatable structure of a crystal

25
Q

coordination number

A

number of atoms that surround a given atom in a lattice

26
Q

what are the 3 types of a simple cubic unit cell

A

simple cubic, body-centered, face-centered

27
Q

the edge length of a simple cubic

A

2r

28
Q

the coordination number of a simple cubic

A

6

29
Q

atom per unit cell of simple cubic

A

1

30
Q

edge length of body-centered

A

4r/square root 3

31
Q

coordination number of body-centered

A

8

32
Q

atom per unit cell of body-centered

A

2

33
Q

edge length of face-centered

A

squareroot 8 *r

34
Q

coordination number of face-centered

A

12

35
Q

atom per unit cell of face-centered

A

4

36
Q

what is the angle of a simple cubic unit cell

A

90