acids and bases up to %ionization Flashcards

1
Q

Bronsted acid

A

a substance that is capable of donating a proton

HA –> H+ + A-

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2
Q

Bronsted base

A

a substance that is capable of accepting a proton

B + H –> BH+

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3
Q

Conjugate acid

A

an acid formed when a base accepts a proton

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4
Q

Conjugate base

A

a base formed when an acid donates a proton

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5
Q

conjugate pair

A

an acid and a base that only has a proton as their difference. E.G H2SO4 –>

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6
Q

Diprotic and Triprotic

A

Diprotic is a substance that has 2 donatable protons

Triprotic has 3

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7
Q

Amphoteric

A

a substance that can behave like an acid or a base depending on what it reacts with

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8
Q

An electrolyte

A

An electrolyte is any substance that can be dissolved in water to give positive and negative ions

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9
Q

Is water an electrolyte

A

water is a weak electrolyte because it can autoionize to a small extent

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10
Q

Equilibrium constant

A

the equilibrium constant explains that at equilibrium, the concs of the forward and reverse reaction remains the same even though the reaction is still occurring
It is represented by K

K= [products] / [reactant]

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11
Q

Kw

A

This is the equilibrium constant of water.

Kw= [OH-] [H+] = 10^-14 at 25 celsius

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12
Q

At 25 celsius, what is the concentration of water

A

10^-14 M

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13
Q

At 25 celsius, what is the concentration of H+ in water

A

10^-7 M

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14
Q

pH

A

The measure of acidity

pH= -log[H+]

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15
Q

Strong acid and base

A

A strong acid or base is one that can completely ionize in water

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16
Q

ionization

A

the breakdown of substances into positive and negative ions

17
Q

weak acid and base

A

A weak acid or base does not completely ionize in water. They can approach 100% ionization but can’t reach it.

18
Q

Relationship between concentration and weak acid/base strength

A

As the concentration decreases, the strength of the weak acid/base increases. Meaning that at very low concentrations, weak acids/bases can ionize more but not completely. The lowest Ka or Kb is the strongest.

19
Q

are conjugates weak or strong?

A

conjugate acids/bases are always weak

20
Q

examples of strong acids

A

HCLO4, HCLO3, H2SO4, HNO3, HI, HBR, HCL

21
Q

examples of weak bases

A

NaOH, KOH, LiOH, Sr(OH)2, Br(OH)2 etc

22
Q

Ka

A

Ka is the strength of the acid. It is also referred to as the acid dissociation constant so the higher Ka is, the stronger the weak acid.

Ka= [products]/[reactant]

23
Q

how do we determine the pH of a weak acid when Ka is available,

A

use the ice table

24
Q

% ionization

A

It is used to show how much acid was ionized.

% ionization = [ionized acid]/[initial conc] x 100