Inosilicates: Pyroxenes Flashcards

1
Q

Inosilicates

A

A group of minerals whose defining characteristic is their chain arrangement of silica (SiO4) tetrahedra.

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2
Q

Single Chain Inosilicates

A

Pyroxenes

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3
Q

Double chain Inosilicates

A

Amphiboles

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4
Q

Pyroxenes General Formula

A

X Y Si2 O6

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5
Q

2 main solid solution minerals

A

Augite (Au) - Diopside (Di) CaMg, Hedenbergite (He) CaFe

Hypersthene (Hy) - Enstatite (En) Mg2, Ferrosilite (Fs) Fe2

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6
Q

Augite (Au)

A

Solid solution of:
Diopside (Di) CaMg
Hedenbergite (He) CaFe

A common Clinopyroxene

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7
Q

Hypersthene (Hy)

A

Solid solution of:
Enstatite (En) Mg2,
Ferrosilite (Fs) Fe2

A common Orthopyroxene

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8
Q

Enstatite (En)

A

Magnesium Pyroxene

Mg2 Si2 O6

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9
Q

Ferrosilite (Fs)

A

Iron Pyroxene

Fe2 Si2 O6

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10
Q

Diopside (Di)

A

Calcium Magnesium Pyroxene

Ca Mg Si2 O6

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11
Q

Hedenbergite (He)

A

Calcium Iron Pyroxene

Ca Fe Si2 O6

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12
Q

3 rare pyroxenes

A

Aegirine - Na Fe Si2 O6
Jadite - Na Al Si2 O6
Omphacite

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13
Q

Aegirine

A

Na Fe Si2 O6

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14
Q

Jadeite

A

Na Al Si2 O6

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15
Q

Structure of Pyroxenes

A

Pyroxenes are formed by series of SiO4 tetrahedra sharing a common oxygen on two corners forming a single chain parallel to the c-axis. These chains are liked laterally with octahedron layers (100 plane) which contain the cation

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16
Q

Orthopyroxene minerals composition

A

Orthopyroxenes contain a solid solution of En-Fs
Enstatite-Ferrosilite
Hypersphene is the most common orthopyroxene mineral formed

17
Q

Clinopyroxenes mineral composition

A

Contain Calcium

Diopsite + Hedenbergite With some En-Fs

18
Q

Exsolution

A

process through which an initially homogeneous solid solution separates into at least two different crystalline minerals without the addition or removal of any materials. In most cases, it occurs upon cooling below the temperature of mutual solubility or stability of the solution.

19
Q

Miscibility

A

Miscibility is the property of two substances to mix in all proportions, forming a homogeneous mixture.

20
Q

Orthopyroxene Crystal System

A

Orthorhombic

21
Q

Clinopyroxene crystal system

A

Monoclinic

22
Q

Orthopyroxene colour in thin sections

A

Pale, subtle pinkish to greenish pleochroism in some

23
Q

Clinopyroxene colour in thin sections

A

Colourless or grey/pale green/pale brown: darker if Fe rich

24
Q

Pyroxene form in thin sections

A

Subhedral stubby prisms, basal sections 4-8 sided

25
Q

Pyroxene relief in thin sections

A

High positive

26
Q

Pyroxene cleavage in thin sections

A

2 good cleavages at 90 degrees to one another parallel to prism faces

27
Q

Orthopyroxene birefringence in thin sections

A

Weak First order yellow

28
Q

Clinopyroxene birefringence in thin sections

A

Strong 2nd order green and red

29
Q

Orthopyroxene extinction in thin sections

A

PARALLEL

30
Q

Clinopyroxene extinction in thin sections

A

OBLIQUE

31
Q

Orthopyroxene twinning in thin sections

A

rare

32
Q

Clinopyroxene twinning in thin sections

A

Common

33
Q

Clinopyroxene distinguishing features in thin sections

A

2 good cleavages at ~90o, high birefringence, twinning and oblique extinction.

34
Q

Orthopyroxene distinguishing features in thin sections

A

2 good cleavages at 90, low birefringence, parallel extinction.

35
Q

Paragenisis of pyroxenes

A

Ultrabasic rocks often with olivine