Crystallography Flashcards
What is a lattice
A lattice is a series of points that are arranged in a distinct pattern. A crystal lattice structure is similar to a lattice, but instead of points, it is composed of a series of atoms.
Unit cell
The smallest unit that describes the symmetry and distribution of the lattice
Motif
Atomic arrangement in each unit cell
Structure
Lattice + Motif
5 2D Lattice types
Primitive Square Lattice Regular Primitive Lattice Oblique Primitive Lattice Rectangular Centered Lattice Hexagonal Primitive Lattice
Glide plane
Mirror + Translation
4 types of Rotational symmetry
2 fold/Diad
3 fold/Triad
4 fold/Tetrad
6 fold/Hexad
3 rules of a unit cell
Same symmetry
Edges coincide
Smallest that corresponds
7 Crystal Systems + Angle + Faces
Cubic a=b=c / a1=a2=a3 α=β=γ=90° Tetragonal a=b≠c / a1=a2≠c α=β=γ=90° Orthorhombic a≠b≠c α=β=γ=90° Monoclinic a≠b≠c α=γ=90° β≠90° Triclinic a≠b≠c α≠β≠γ≠90° Triagonal a1=a2=a3≠c α=β=90° γ=120° Hexagonal a1=a2=a3≠c α=β=90° γ=120°
14 Bravais Lattices
Cubic-> Primitive, Body Centered (bcc), Face Centered (fcc)
Tetragonal-> Primitive, Body Centered
Orthorhombic-> Primitive, Body-Centered, Face Centered, ‘c’ Centered
Monoclinic-> Primitive, ‘c’ Centered
Triclinic-> Primitive
Triagonal-> Primitive
Hexagonal-> Primitive
3 Types of Crystal Symmetry
Planar/Mirror-> Each side of the plane is a mirror of the other
Axial/Rotational -> the Same position reached how many times in the rotation of the axis
Centers of Symmetry -> Same faces on opposite sides
Miller Indicies
The system of crystallographic indexing for crystal faces. If it never crosses an axis the value is 0, if it crosses at the full length it is 1 and if it crosses at half it is 2 and so on. If it is negative then there is a bar over it. It is given in the format (hkl) or (hkil).