Inornganic Chem + periodic table Flashcards

1
Q

What colour does sodium turn in a flame test?

A

yellow-orange

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2
Q

What colour does caesium turn in a flame test?

A

blue-violet

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3
Q

What colour does potassium turn in a flame test?

A

lilac

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4
Q

What colour does lithium turn in a flame test?

A

red

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5
Q

What colour does rubidium turn in a flame test?

A

reddish-purple

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6
Q

What colour does magnesium turn in a flame test?

A

intense white flame

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7
Q

What colour does strontium turn in a flame test?

A

red

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8
Q

What colour does calcium turn in a flame test?

A

orange-red

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9
Q

What colour does barium turn in a flame test?

A

pale green

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10
Q

What happens to the atomic radius as you go down group 2 and why?

A

atomic radius increases
each extra electron shell is further away

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11
Q

what happens to ionisation energy as you go down group 2?

A

ionisation energy decreases
outer electrons are further away and experience less attraction to the nucleus

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12
Q

what happens to melting point as you go down group 2?

A

melting point decreases
ion cores have larger radii down the group
free electrons experience less attraction to the nuclei because of the larger radii
bonding is weaker, so the melting point is lower

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13
Q

whats formed when group 2 metals react with water

A

a metal hydroxide and hydrogen gas is produced
reactivity increases going down group 2 because lower elements have lower ionisation energies

(beryllium is an exception, if it were to lose 2 electrons it would be tiny and have a very high charge density, this would make it unstable and so beryllium doesnt react with water)

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14
Q

what happens to the solubility of salts going down group 2?

A

solubility of hydroxides increases going down
solubility of sulfates decreases going down

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15
Q

whats formed when group 2 metals react with acids?

A

salt and hydrogen gas
salts produced become less soluble as you go down the group

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16
Q

whats formed when group 1 and group 2 carbonates undergo thermal decomposition?

A

metal oxide & carbon dioxide

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17
Q

whats formed when group 1 and group 2 nitrates undergo thermal decomposition?

A

metal oxide, nitrogen dioxide & oxygen

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18
Q

what happens to the thermal decomposition of group 1 and 2 carbonates & nitrates going down the group?

A

they get more stable as you go down the group
more energy is required for thermal decomposition to occur

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19
Q

what is the charge density like on a smaller charged particle?

A

they have a greater charge density compared to a larger charged particle

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20
Q

what happens to the charge density of the elements going down group 1 and 2?

A

the charge density gets lower as the size of the ions get bigger

21
Q

what affect does polarisation have on a carbonate ion or a nitrate ion?

A

the more polarised the ion is, the easier it is for it to decompose

22
Q

describe the reactions of group 2 oxides and water

A

group 2 oxides steadily react with water
the reaction produces a metal hydroxide salt. the salt dissociates into metal ions and hydroxide ions, giving the solution an alkaline pH

23
Q

describe group 2 solubility down the group

A

group 2 hydroxides become more soluble down the group so the solutions become more strongly alkaline down the group

24
Q

does beryllium oxide react with water?

25
does magnesium oxide react with water?
yes, but very slowly
26
what phase is fluorine in?
gas
27
what phase is chlorine in?
gas
28
what phase is bromine in?
liquid
29
what phase is iodine in?
solid
30
what happens to electronegativity down group 7
decreases - atomic radius increases and so electrons experience less attraction to the nucleus electrons become further away from the nucleus and so experience a lower attraction
31
what happens to boiling point going down group 7
increases elements have more electron going down group 7 this causes an increase in LDF, stronger LDF means greater intermolecular forces
32
which of the halogens is the most oxidising agent?
fluorine as it is the most electronegative
33
what happens if an elemental halogen is added to a halide solution?
the heavier halide will be displaced this is because the lighter halide has a greater preference to be the halide ion as its more electronegative
34
describe halide reactions with sulfuric acis
halides react differently with sulfuric acid depending on the reducing ability
35
what colour precipitate do chloride ions and silver nitrate form
white
36
what colour precipitate do bromide ions and silver nitrate form?
cream
37
what colour precipitate do iodide ions and silver nitrate form
yellow
38
what happens when silver chloride is added to ammonia
silver chloride should redissolve
39
what happens when silver bromide is added to ammonia
silver bromide should redissolve slowly and will need a lot of ammonia
40
what happens when silver iodide is added to ammonia
silver bromide should not dissolve
41
whats formed when fluoride reacts with sulfuric acid
produces HF
42
whats formed when chloride reacts with sulfuric acid
produces HCl
43
whats formed when bromide reacts with sulfuric acid
produces Br2 and some SO2
44
whats formed when iodide reacts with sulfuric acid
produces I2 immediately and then will reduce the sulfur to H2S
45
whats formed when chlorine reacts with water
HCl + HClO then can go to: 2H + ClO- + Cl- this reaction is used in water treatment to kill bacteria
46
what happens when chlorine reacts with water in sunlight
the chlorate ion produced will decompose to produce hydrochloric acid and oxygen
47
what are the risks of adding chlorine to water
chlorine gas is toxic liquid chlorine that touches eye or skin will burn chlorine may react with organic compounds and form carcinogenic hydrocarbons
48
how is bleach made?
by adding chlorine to sodium hydroxide