Inorganic Chemistry Flashcards

1
Q

What observations are made when alkali metals react with water

A

-lithium, sodium and potassium react vigorously in water
-reaction of the alkali metals with water produced hydrogen, causing fizzing

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2
Q

Word equation of alkali metals (sodium) reacting with water

A

2Na(s) + 2H2O(l) -> 2NaOH(aq) +H2(g)

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3
Q

How do alkali metals react with the air

A

They react with the oxygen to form metal oxides

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4
Q

What does each alkali metal form when reacted with oxygen

A

-lithium forms Li2O
-sodium reacts to form Na2O and Na2O2
-potassium reacts to form K2O2 and KO2

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5
Q

Why do group 1 elements become more reactive down the groups

A

-they have 1 electron in their outer shell
-further down group 1, the outermost electron is in a shell that is further from the nucleus
-attraction between outermost electron and nucleus becomes less
-as atoms get bigger when you go down group 1 elements, they become more reactive

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6
Q

How do properties of group 7 elements change as you go down the group

A

-elements become darker and have a higher boiling point
-this is because the intermolecular forces are greater when the size of the atoms increase

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7
Q

Colour, state of chlorine

A

Green, gas

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8
Q

Colour and state of bromine

A

Red-brown, gas

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9
Q

Colour and state of iodine

A

Dark grey, solid

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10
Q

Why does the reactivity of halogens decrease as you go down the group

A

-group 7 elements have 7 electrons in their outer shell, they can gain one electron to form an ion
-it is harder to attract the extra electron as you go down the group, as the outer shell if further away from the nucleus, as the attraction between the outer shell electron and the nucleus decreases when the atom is larger

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11
Q

What is a displacement reaction

A

When a more reactive element pushes out a less reactive element from a compound

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12
Q

Name of the loss of electron and gain in electrons

A

Loss of electrons:oxidation
Gain in electrons:reduction

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13
Q

What do oxidising agents and reducing agents do

A

Oxidising agents accept electrons and gets reduced
Reducing agents donates electrons and gets oxidised

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14
Q

What is it called when a reduction and oxidation happens at the same time

A

Redox reaction

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15
Q

Earth’s gas proportion

A

78% nitrogen
21% oxygen
0.04% carbon dioxide
1% argon(nearly)

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16
Q

Practical to investigate the proportion of oxygen in the atmosphere

A

-soak iron wool in acetic acid
-push the wool into a measuring cylinder and invert it into a beaker of water
-record the starting position of the water using the scale
-over time, the level of the weather in the measuring cylinder will rise, as iron reacts with the oxygen to make iron oxide
-water rises to fill up the space the oxygen took up
-leave measuring cylinder for a week or nail the water level stops changing
-record finishing position of the water
((Start volume - final volume)/start volume) x 100

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17
Q

Experiment to investigate the proportion of oxygen in air using phosphorus

A

-placate phosphorus in a tube and attach a glass syringe at either end
-make sure on syringe is filled with air and the other is empty
-heat the phosphorus and use the syringes to pass air over it, the phosphorus will react with oxygen in the air to make phosphorus oxide
-as it reacts, the amount of air in the syringes will decrease
-measure the starting and final volumes of air using the scale on one of the syringes
-calculate the percentage of oxygen in the air

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18
Q

What happens when magnesium is burnt to react with oxygen

A

-magnesium burns with a bright white flame in air and the white powder that is formed in magnesium oxide
-magnesium oxide is slightly alkaline when it’s dissolved in water
2Mg + O2 -> 2MgO

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19
Q

What happens when hydrogen is burnt to react with oxygen

A

-Hydrogen burns easily in oxygen, can be explosive
-orange/yellow flame and the only product is water
2H2 + O2 -> 2H2O

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20
Q

What happens when sulfur is burned to react with oxygen in the air

A

-sulfur burns in air or oxygen with a pale blue flame and produced sulfur dioxide
-sulfur dioxide s acidic when it’s dissolved in water
S + O2 -> SO2

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21
Q

What do greenhouse gases do

A

They absorb most of the heat that would normally be radiated out into space, and re-radiate it in all directions, including back to the earth

22
Q

Universal indicator colours

A

Acid is 0, neutral is 7 and alkali is 14
Goes in the colour of the rainbow where 7 is green

23
Q

Litmus paper colours

A

Red in acidic solutions, purple in neutral and blue in alkaline solutions

24
Q

Phenolphthalein colours

A

Colours in acidic solutions and bright pink in alkaline solutions and neutral

25
Q

Methyl orange colours

A

Red in acidic solutions, orange in neutral and yellow in alkaline solutions

26
Q

Name of reaction between acid and base

A

Neutralisation

27
Q

what is chromatography used for

A

-method used by chemists to separate out mixtures

28
Q

how to carry out paper chromatography

A

-draw a line near the bottom of a sheet of filter paper)pencil as they are insoluble
-add spots of different inks to the line at regular intervals
-loosely roll the sheet up and put it in a beaker of solvent(water)
-make sure the level of solvent is below the baseline(so ink doesn’t dissolve into the solvent
-place a lid on top of the container to stop solvent evaporating
-the solvent will seep up the paper, carrying the inks with it
-each different dye in the inks will move up the paper at a different rate and form a spot in a different place
-when the solvent has nearly reached the top of the paper take the paper out of the beaker and leave it to dry
-end results is a pattern of spots called a chromatogram

29
Q

how to calculate the Rf value for each chemical

A

Rf = distance travelled by solute/distance travelled by solvent

30
Q

distillation

A

-solution is heated
-the part of the solution that has the lowest boiling point evaporates
-the vapour is then cooled, condenses(turns back into a liquid and is collected)
-rest of the solution is left behind in the flask

31
Q

neutralisation

A

-add excess solid to the acid
-stir the mixture to make sure reaction is complete
-filter the mixtures to remove excess
-transfer the solution into an evaporating dish
-heat up the filtrate until saturated
-check saturation point using a glass rod
-if crystals form then saturation point has been reached
-allow to cool and crystalise
-filter to remove crystals
-dry crystals in a warm oven

32
Q

titration

A

-using a pipette, add alkali(usually 25 cm3) to a conical flask, along with two or three drops of indicator
-fill a burette with the acid
-using burette add the acid to the alkali a bit at a time, giving the conical flask a regular swirl
-the indicator changes colour when all the alkali has been neutralised
-record the volume of acid used to neutralise the alkali
-repeat without Indicator

33
Q

precipitation

A

-mix the solutions
-stir the mixture
-filter off the precipitate
-wash with distilled water
-dry the solid in warm oven

34
Q

metal + acid

A

salt +hydrogen

35
Q

carbonate + acid

A

salt + carbon dioxide + water

36
Q

alkali + acid

A

salt +water

37
Q

base + acid

A

salt + water

38
Q

are common salts of sodium potassium and ammonium soluble

A

-soluble

39
Q

nitrates solube?

A

yes

40
Q

common chlorides soluble

A

yes except silver and lead

41
Q

common sulfates soluble

A

yes except lead, barium and calcium

42
Q

common carbonates soluble

A

no except sodium potassium and ammonium

43
Q

common hydroxides soluble

A

no except sodium potassium and calcium

44
Q

test for chlorine

A

-chlorine bleaches damp blue litmus paper, turning it white
-might turn red first as chlorine solution is acidic

45
Q

test for oxygen

A

oxygen relights a glowing splint

46
Q

test for carbon dioxide

A

CO2 turns limewater cloudy-bubble the gas through a test tube of limewater

47
Q

test for hydrogen

A

-hydrogen makes a squeaky pop with a lighted splint

48
Q

how to prevent rusting

A

Barrier methods
-painting/coating with plastic to keep -out the water and oxygen
Sacrificial methods
-zinc is often used as a sacrificial metal
-zinc is more reactive than iron, further up in the reactivity series
-zinc will be oxidised instead of iron
-a coating of zinc can be sprayed onto the object-known as galvanising
-big blocks of zinc can be bolted to the iron, used on ships’ hulls or on underground iron pipes

48
Q

reactivity series

A

potassium
sodium
lithium
calcium
magnesium
aluminium
carbon
zinc
iron
Tin
Lead
Hydrogen
copper
silver
gold
Please stop lions calling me a careless zebra, instead try learning how copper saves gold

48
Q

test for ammonia

A

-ammonia turns damp red litmus paper blue

49
Q

equation for rust

A

iron + oxygen + water ->hydrated iron III oxide (rust)