Important Equations chemistry Flashcards

1
Q

enzyme velocity

A

V =

Vmax * [S])/(Km + [S]

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2
Q

osmotic pressure

A

Π = iMRT

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3
Q

Energy of electron - Bohr’s Model of the Hydrogen Atom

A

E = -Rh/n²

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4
Q

Electromagnetic energy of photons - Bohr’s Model of the Hydrogen Atom

A

E = hc/λ

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5
Q

Equilibrium constant for:

aA + bB ⇌ cC + dD

A

Kc = ([C]^c[D]^d)/([A]^a[B]^b)

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6
Q

calorimetry heat equation

A

q = mc∆T

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7
Q

Standard heat of reaction (∆H°rxn) - using heat of formations

A

∆H°rxn = (sum of ∆H°f of products) - (sum of ∆H°f of reactants)

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8
Q

Standard heat of reaction (∆H°rxn) - using bond dissociation energies

A

∆H°rxn = ∑∆Hbonds broken - ∑∆Hbonds formed

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9
Q

entropy

A

∆Suniverse = ∆Ssystem + ∆Ssurroundings

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10
Q

Gibbs free energy (G) - thermodynamics

A

∆G = ∆H - T∆S

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11
Q

Reaction Quotient for:

aA + bB ⇌ cC + dD

A

Q = ([C]^c x [D]^d)/([A]^a x [B]^b)

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12
Q

Boyle’s Law

A

PV = k; P₁V₁ = P₂V₂

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13
Q

Charles’s Law

A

V/T = k; V₁/T₁ = V₂/T₂

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14
Q

Gay-Lussac’s Law

A

P/T = k; P₁/T₁ = P₂/T₂

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15
Q

Avogadro’s Principle

A

n/V = k; n₁/V₁ = n₂/V₂

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16
Q

Combined Gas Law

A

(P₁V₁)/T₁ = (P₂V₂)/T₂

17
Q

Ideal Gas Law

A

PV = nRT

18
Q

Van der Waals equation of state

A

Partial Pressures:

Pt = Pa + Pb + Pc ….

19
Q

root-mean-square speed

A

Urms = √(3RT/M)

20
Q

Freezing-Point depression

A

∆T = i x (Kf) x molality

21
Q

Boiling-Point elevation

A

∆T = i x (Kb) x molality

22
Q

diffusion formula

A

r₁/r₂ = (1/2) * [√(m₂/m₁)]

23
Q

percent composition by mass

A

(mass of solute/mass of solution) x 100%

24
Q

mole fraction

A

(number of moles of compound)/(total number of moles in system)

25
Q

molarity

A

(number of moles of solute)/(liter of solution)

26
Q

molality

A

(number of moles of solute)/(kilogram of solvent)

27
Q

normality

A

(number of gram equivalent weights of solute)/(liter of solution)

28
Q

pH equation

A

pH = -log[H⁺]

29
Q

pOH equation

A

pOH = -log[OH⁻]

30
Q

ionic product for water, Kw

A

Kw = [H⁺] x [OH⁻]

31
Q

Henderson-Hassebalch equation (buffer regions) - pH

A

pH = pKa + log([A-]/[HA])

32
Q

Henderson-Hassebalch equation (buffer regions) - pOH

A

pOH = pKb + log([conjugate acid]/[weak base])

33
Q

standard electromotive force (E°cell)

A

E°cell = E°cathode - E°anode

34
Q

Gibb’s free energy - electrochemistry

A

∆G = -nF(Ecell)