Identification of Ions and gases Flashcards
List aqueous cations
Ammonium, copper (II), Iron (II), Iron (III) and zinc
How are cations identified?
With Aqueous sodium hydroxide and aqueous ammonia
Test for Ammonium cation and positive result
Add dilute sodium hydroxide, heat it.
Ammonia gas is released which has a pungent smell, damp red litmus paper turns blue
Test for Copper (II) and positive result
Add dilute sodium hydroxide or ammonia solution. A blue precipitate forms
Test for Iron (II) and positive result
Add dilute sodium hydroxide or ammonia solution. A pale green precipitate forms
Test for Iron (III) and positive result
Add dilute sodium hydroxide or ammonia solution. A red brown precipitate forms
Test for Zinc and positive result
Add dilute sodium hydroxide or ammonia solution. A white precipitate forms.
What happens when a cation is given to identify but a precipitate doesn’t form when sodium hydroxide is added?
If there is no precipitate, gas may have formed. Use the litmus test on this gas to confirm that it is ammonia.
List Anions
Carbonate, Chloride, Nitrate, Sulfate
Test for Carbonates and positive result
Add dilute hydrochloric acid and limewater. Bubbles that give off gas will turn limewater milky
Test for Chlorides and positive result
Add the same volume of nitric acid and chloride, add aqueous silver nitrate. A white precipitate will form
Test for Nitrates and positive result
Add sodium hydroxide, then aluminium and warm gently. Ammonia gas is released which has a pungent smell, damp red litmus paper will turn blue
Test for Sulfates and positive result
Add dilute hydrochloric acid and then a barium salt solution (could be chloride or nitrate). A white precipitate will form.
what to do when given an anion to identify?
Divide in four test tubes and conduct the four tests above for each test tube.
Colour of bromide ions positive
Pale yellow precipitate
Test for ammonia gas
Damp red litmus paper turns blue
Test for carbon dioxide
Pass it through limewater, it will turn milky white
Test for chlorine gas
Damp blue litmus paper turns white
Test for hydrogen gas
Expose it to a lighted splint, a loud pop sound is heard
Test for oxygen gas
Expose it to a glowing splint, the splint will relight