ideal gases + 1st law thermo Flashcards
Zeroth Law of Thermodynamics
for two objects in thermal equilibrium, they must be at the same temperature, and there is no net transfer of thermal energy between the two objects when they are placed in thermal contact.
absolute zero
the temperature at which all substances have minimum internal energy
thermodynamic temperature scale
temperature scale that is independent of the property of any particular substance AND has an absolute zero
basic assumptions of kinetic theory of gases
- perfectly elastic collisions between molecules and walls of container
- total volume of the gas molecules is negligible compared to the volume occupied by the gas
- the duration of a collision is negligible in comparison to the time between collisions
- there are a large number of molecules in constant random motion (this)
- imf between molecules are negligible
specific heat capacity
thermal energy transferred per unit mass per unit change in temperature
specific latent heat
thermal energy transferred per unit mass during the change of state at constant temperature
SLH of vaporisation/fusion
thermal energy transferred per unit mass during the change in state between [liquid and gas]/[solid and liquid] at constant temperature
internal energy of a system
sum of random distribution of kinetic energies and potential energies associated with the molecules of the system (no potential energies for ideal gas)
First Law of Thermodynamics
the increase in internal energy of (ΔU) a system is equal to the sum of the heat supplied to the system (q) and the work done on the system (W)