Ideal gases Flashcards

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1
Q

Mole def

A

One mole is the amount of substance that has the same number of particles as there are atoms in 0.012kg of carbon 12

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2
Q

Mass of molecule formula

in terms of RAM, Av

A

Mass of molecule= RAM/ Avagadro

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3
Q

Number of moles formula

A

Mass/ RAM

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4
Q

Number of particles formula

A

Number of moles * Avagadro

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5
Q

Ideal gas definiton

A

An ideal gas is one that obeys PV∝T at all pressures volumes and temperatures

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6
Q

Boyles law

A

V∝1/P

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7
Q

Charle’s law

A

V∝T

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8
Q

Pressure law

A

P∝T

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9
Q

Ideal gas equation

A

PV= nRT
PV= NKT

n is number of moles
N is number of molecules

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10
Q

K is?

A

Boltzmann’s constant
K=R/ Avagadro

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11
Q

Ideal gas equation is only used for?

A

real gases well above liquefaction temp with not high pressure

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12
Q

4 Basic assumptions of kinetic theory of gases

A
  1. Gases contain large molecules moving randomly with negligible attraction between molecules
  2. Forces between particles are negligible, except during collisions- which are perfectly elastic
  3. Volumes of the particles is negligible compared to the volume occupied by the gas
  4. The time of collision by a particle with the container walls is negligible compared with time between collisions
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13
Q

What are the 4 assumptions about

A

Attraction between molectules
Forces between particles
Volume of particle
Time of collision of particle

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14
Q

Derivation of PV= 1/3Nm<c²>

6 points

A
  1. ΔP after hitting a wall at 90°. ΔP= -2mc
  2. Time between collisions. t= 2l/ c
  3. Combine to find ΔP/t= F. F= 2mc/ (2l/c) = mc²/l
  4. Pressure P= F/A. = mc²/l ÷ l² = mc²/ l cubed
  5. Different speeds of dif molecules, use <c²> and NM
    P= Nm<c²>/ l cubed
  6. Three different directions of molecules
    P= 1/3 Nm<c²>/ l cubed
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15
Q

Pressure exerted by gas formula

A

P= 1/3Nm<c²>/ V

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16
Q

Mean speed?

A

<c>= all speeds/ no. of speeds
</c>

17
Q

Mean square speed

A

<c²>= all speeds squared/ number of speeds

18
Q

R.m.s

A

√<c²>= root of <c²>

19
Q

Derive kinetic energy= 3/2kt

3 points

A
  1. state two formulas: PV= 1/3Nm<c²> and PV= NkT
  2. Equate
  3. Simplify to get kinetic energy
20
Q

Why is the value of Boltzmann’s constant so small

A

Because the increase in kinetic energy of a molecule is very small for every incremental increase in temperature

21
Q

What is Boltzmann’s constant

A

Relates the properties of microscopic particles (ke of gas molecules) to their macroscopic properties (temperature)