HYS - CH10: Acids and Bases Flashcards

1
Q

general acid base reaction

A

acid + base –> salt + water

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2
Q

arrhenius definition of acids and bases

A

acids are hydronium ion donors
bases are hydroxide ion donors

doesnt explain all of them and only works with water

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3
Q

lewis definition

A

acids accept an electron pair
basis donate an electron pair

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4
Q

bronsted lowry defintion

A

acids donate a proton
bases accept a proton

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5
Q

pH depends on

A

H+ (acidic) nd OH- (basic)

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6
Q

hyrolysis of a salt to form a basic solution example

A

NaF

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7
Q

hydrolysis of a salt to form an acidic solution ex

A

proton binds to water forming hydronium

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8
Q

conjugate acid base pair

A

exists in a state where it has (acid) or lacks (basic) a proton

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9
Q

identify the conjugate acid and base pair and the conjugate base and acid pair

A

H3PO4 is the acid bc it later donates an proton and looses it to become the conjugate base

H3O+ is the conjugate acid becuase it accepts a proton after being a base

H20 is the base becuase it later accepts a proton when it becomes a conjugate acid

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10
Q

ampotheric

A

act as acid or base

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11
Q

Keq, Ka, Kb

A

help us quantify if reaction goes forward or backwards based

Ka for acids - dissociation constant
Kb for bases - dissociation constant

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12
Q

which species are included in equilibrium constant

A

only aqueous

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13
Q

general Kb formula

A
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14
Q

general Ka formula

A
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15
Q

acid base chemistry is centered on interaction with

A

water

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16
Q

Kw at STP

A

equilibrium constant of water

standard conditions; 25 C and 1 atom
Kw = 1 x 10^-14

17
Q

unit change in Ph causes

A

10 fold change in acidity

18
Q
A
19
Q

if [H30+] is = [OH-] at STP then its
if [H30+] is > [OH-] at STP then its
if [H30+] is < [OH-] at STP then its

A

if [H30+] is = [OH-] at STP then its neutral
if [H30+] is > [OH-] at STP then its acidic
if [H30+] is < [OH-] at STP then its basic

20
Q

how to find pH (power of hydrogen) and pOH (power of hydroxide)

How to find the pka and the pkb

A
21
Q

pka + pkb =
ph+ pOH =
Ka*Kb =

A

Ka*Kb = Kw = 10^14
pka + pkb = 14
ph+ pOH = 14

22
Q

polyprotic acid

A

A substance capable of donating more than one proton is known as Polyprotic Acid. Diprotic and Triprotic are specific types of polyprotic acid capable of donating two and three protons, respectively.

23
Q

if Ka is large then kb must be
if kb is large then ka must be

A

if Ka is large then kb must be small
if kb is large then ka must be large

24
Q

strong acid and strong base

A

ka >1 is strong acid
Kb > 1 is a strong base

25
Q
A
26
Q

strong acids and strong bases will _____ dissociate in aqeous solutions

A

will completely dissociate

dissociation - the breaking up of a compound into simpler constituents that are usually capable of recombining under other conditions.

27
Q

weak acids and weak bases will _____ dissociate in aqeous solutions

A

will not completely dissociate in aqeous solutions

28
Q

all strong acids

A

hydrochloric acid (HCl)
hydrobromic acid (HBr)
hydroiodic acid (HI)
sulfuric acid (H2S04)
nitric acid (HNO3)
chloric acid (HClO3)
perchloric acid (HClO4)

29
Q

all strong bases

A

sodium hydroxide (NaOH)
potassium hydroxide (KOH)
hydroxides formed from group 1 metals
cesium hydroxide (CsOH)
calcium hydroxide (Ca(OH2)
barium hydroxide (Ba(OH)2)
stronium hydroxide (Sr(OH)2)

30
Q

if you but a strong acid in aqeous solution they will___ protons

A

donate

31
Q

the conjugate cations of the strong bases are considered

A

inert

32
Q

weak acids and weak bases

A