Hydrothermal Vent Origin of Life Model Flashcards
and other extreme environment considerations
7 stage of fluid movement at hydrothermal vents
1) cold water seeps into crustal cracks
2) O and K removed from seawater
3) Ca, (SO4)2-, and Mg removed from fluid
4) Na, Ca, K from crust added to fluid
5) Fluid at hottest temp = Cu, Z, Fe, S from crust added to fluid
6) hot fluid rises, carrying dissolved metals through crust
7) cold-oxidated- and hot-reduced- waters mix, forming black metal-sulfide minerals
What is serpentinization?
Hydration and metamorphic transformation of ultramafic rock
why is serpentinization important?
it produces hydrogen gas, which reacts with CO2 to create organics
Where is inorganic carbon dominant at hydrothermal vents?
Center of vent, where the temperature is hottest
Where is organic carbon dominant at hydrothermal vents?
flanks of the vent, where the temperature is cooler
What is a Fischer-Tropsch reaction
two step conversion of CO into organic carbon
What are the two steps in a Fischer-Tropsch reaction?
1) H2 and CO2 convert to water and CO
2) CO and more H2 convert to Methane and water
(there are other steps two possibilities)
How does Hydrothermal Vent theory address dilute concentrations in seawater?
Mineral Templates , surface metabolism model
(mineral surfaces collect dissolved species, causing them to concentrate and act as catalyst)
How does mineral surface catch dissolved species?
1) the surfaces are not fully bonded,
2 ) oxygen in water will fill those gaps in the surface
3) hydrogen will rearrange to create hydroxyl (OH-)groups
What charges are possible on a oxide mineral surface?
positive, neutral, negative
What determines the charge on a oxide mineral surface?
pH
more acidic = positive charge
more basic = negative charge
Why is charge of an oxide mineral surface important?
It allows different anion and cations to concentrate on the surface
What charges will clay surfaces have?
net negative, potential for sections of positive due to hydroxyl groups at edges sites
What causes changes in clay surfaces charges?
net negative areas = vacancies/holes due to elemental substitutions
edge sites = pH of solution
What are two ways that ice connected to origin of life theories?
1) small lenses of liquid water trapped in the ice allow for very concentrated solutions
2) chirality