Hydrogen Flashcards

1
Q

what is the first element on the periodic table

A

hydrogen

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2
Q

What is the most abundant element in the universe, accounting for about 75% of all mass

A

hydrogen

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3
Q

free H2 is _______

A

scarce

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4
Q

highest energy by ______, but low volumetric ______ ________

A

weight
volumetric energy density

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5
Q

how much more energy by weight does hydrogen have compared to gasoline

A

3 times

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6
Q

what can hydrogen be used to make

A

fertilizers, steel, fuel in trucks, store energy, make electricity, multiple abundant fuel sources

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7
Q

what goes into a fuel cell and what comes out
is there combustion?

A

Hydrogen and oxygen in
electricity and water out
no combustion

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8
Q

Fuel cells and electrolyzes are known as hydrogen consumption or hydrogen production

A

fuel cells are hydrogen consumption
electrolyzes are hydrogen production

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9
Q

what goes into and out of the electrolyzers

A

electricity and water in
hydrogen and oxygen out

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10
Q

the electrolyzers operate like a fuel cell in __________

A

reverse

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11
Q

what is grey hydrogen

A

produced by steam methane reformation (SMR) without carbon capture ad sequestration (CCS)

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12
Q

What is blue hydrogen

A

produced from fossil fuels by steam methane reformation (SMR), pyrolysis or other processes with carbon capture and sequestration

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13
Q

what is green hydrogen

A

produced from water by electrolysis using renewable electricity such as hydroelectricity, wind or solar

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14
Q

what is white hydrogen energy

A

produced from water by electrolysis or high temperatures from nuclear energy

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15
Q

What are hard to decarbonize industries

A

steel, cement, and ammonia industries

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16
Q

What are the 6 hydrogen uses that are included in the hydrogen economy

A

Hard to decarbonize sectors, transportation, energy storage, stationary fuel cells, petroleum refining, and chemicals

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17
Q

describe how transportation fits in the hydrogen economy

A

for heavy duty applications including trucks, trains, and at ports

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18
Q

describe how energy storage fits in the hydrogen economy

A

good for long-term energy storage; improved electric grid efficiency

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19
Q

describe how Stationary fuel cells fits in the hydrogen economy

A

electricity production for cell phone towers, data centers, hospitals and supermarkets

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20
Q

describe how petroleum refining fits in the hydrogen economy

A

largest use of hydrogen produced today

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21
Q

describe how chemicals fits in the hydrogen economy

A

second largest use of hydrogen produced today

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22
Q

What are the advantages of hydrogen

A

highest energy content by weight
reduced greenhouse gas emissions, store renewable power, ability to use for industry and transportation, faster charging time than electric vehicles, reduced air pollution, reliable and flexible power grid support

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23
Q

An advantage of hydrogen is that it has the highest energy content by weight. what state and conditions must be met to realize this advantage

A

has to be high pressure or liquid state to realize this advantage

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24
Q

what are the challenges for large scale hydrogen utilization

A

high initial cost for infrastructure and safety, need consume energy (fossil fuels or renewables) to produce, highly flammable and reactive, difficult to store and transport, limited infrastructure to move and use hydrogen

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25
Hydrogen must be produced from other fuels such as natural gas or from water through ___________ by consuming electricity. Therefore, hydrogen should be called an energy ________ rather than an energy _________
electrolysis carried source
26
what are the hydrogen conversion methods using solar
electrolysis of water, photolytic splitting of water and thermal splitting of water
27
what are the hydrogen conversion methods using wind
electrolysis of water
28
What are the hydrogen conversion methods using biomass
Fermentation, gasification, pyrolysis
29
What are the hydrogen conversion methods using natural gas
pyrolysis, steam reforming, plasma reforming
30
what are the hydrogen conversion methods using oil
gasification and partial oxidation
31
what are the hydrogen conversion methods using coal
partial oxidation and gasification
32
what are the electrochemical conversion methods
electrolysis of water, photolytic splitting of water
33
what ae the biological conversion methods
fermentation
34
what are the thermochemical conversion methods
thermal splitting of water, gasification, pyrolysis, steam reforming, plasma reforming, partial oxidation
35
globally, what conversion methods produced almost 50% of hydrogen. why?
steam methane reforming SMR It is the least expensive, can be blue or green hydrogen, made by natural gas
36
which conversion method is the most desirable method to produce green hydrogen
electrolysis of water
37
what are the disadvantages of electrolysis of water
cost, durability, reliability, safety. no thermodynamic advantage because it consumes electricity more than it produces. Does store energy tho, just cant have 100% efficiency
38
describe the first step of steam-methane reforming
high temperature steam (700-1000) is used to produce hydrogen from a methane source, such a natural gas. The products are hydrogen, carbon monoxide, and a relatively small amount of carbon dioxide. steam reforming is endothermic (heat must be supplied)
39
Describe the second step of steam methane reforming
water-gas shift reaction (WGS), carbon monoxide and steam are reacted using catalyst to produce carbon dioxide and more hydrogen (exothermic)
40
What is the combination of the two reactions in SMR
CH4 + 2H2O = CO2 + H2 +heat
41
SMR can also be used to produce hydrogen from other fuels such as
ethanol, propane, or even gasoline
42
For SMR + water gas shift, how much hydrogen is released to the atmosphere if there is no capture and sequestration
6 ton from 2.2 ton methane input
43
For SMR + water gas shift, how much hydrogen is released to the atmosphere if there is capture and sequestration
about 70% of carbon is captured, so 2.9 ton methane input. 1.5 ton CO2 released, 3.6 ton CO2 CCS
44
The ______ _______ provide a resilient, protected, leak proof reservoir to inject, store, and deliver hydrogen.
salt caverns
45
what are the 3 phases to store hydrogen in salt caverns
leaching phase - inject water to dissolve salt debrining phase - inject more water and pump the salty brine water out filling phase - inject gas and pump out the brine
46
what are the two main ways hydrogen can be stored
physical based, material based
47
storage of hydrogen as a liquid requires cryogenic temperatures because the boiling point of hydrogen at one atmosphere is _______
- 252.8C
48
what are the physical based ways to store hydrogen
compressed gas, cold/cyro compressed, liquid H2
49
what are the material based ways to store hydrogen
absorbent, liquid organic, interstitial hydride, complex hydride, chemical hydrogen
50
what are the 2 main categories of of hydrogen transportation
physical and chemical
51
what are the 2 sub categories of physical transportation of hydrogen
Gaseous H2, liquified H2
52
what are the 3 types of gaseous H2 transportation
compressed H2 tube trailers, pipeline, zeppelin H2 carrier
53
what are the 2 types of liquified H2 transportation
cryogenic liquid trailers, cryogenic liquid ships
54
what are the 5 ways to chemical transport H2
ammonia - ships, train trailers, LOHC - ships, semi trailers, metal hydride trailers
55
Beining the smallest and lightest molecules, In order totransport large amounts of hydrogen it must be either _________ and delivered as a __________ _____, or _______.
pressurized compressed gas, or liquified
56
At the point of hydrogen use, infrastructure components include
compression, storage, dispensers, meters, and contaminant detection and purification technologies
57
what are the 4 methods of clean hydrogen transportation
pipeline route, clean ammonia route, liquified hydrogen route, liquid organic hydrogen carrier route
58
what are the steps to transport hydrogen over long distances
hydrogen liquefaction at -253C - carry by boat - vaporization
59
what are the steps to transport hydrogen in large quantity and over long distances
compress hydrogen - pipeline - storage
60
Ammonia is an efficient way to transport hydrogen as a ________. After reaching its destination, it can be converted back to hydrogen or used as ammonia.
liquid
61
where are the majority of hydrogen cars with fueling stations in the US
California
62
what are the pressures for hydrogen fueling stations
H70 - 700 bar H35 - 350 bar
63
what are the 4 pillars to Saskatchewan hydrogen hive
location, collaborators, integration, and storage
64
what are the 5 leading markets for clean hydrogen end-use opportunities
Heating, power generation and storage, exports, transportation, and industrial processes
65
Describe how hydrogen is used in heating
hydrogen is blended with natural gas or burned directly and is used for residential and commercial use
66
describe how hydrogen is used in power generation and storage
generating electricity using hydrogen turbines and fuel cell generators, and producing hydrogen via electrolysis from intermittent renewables as energy storage medium
67
describe how hydrogen can be used in exports
meeting energy competitiveness and growing international demand
68
describe how hydrogen can be used for transportation
hydrogen fuel cell cars, buses, trucks, trains, aviation, hydrogen combustion engines
69
describe how hydrogen can be used for industrial processes
includes fossil fuel refining and bitumen upgrading, ammonia and fertilizers, chemicals, and liquid synthetic fuels