Hydrocarbons Flashcards
what is an organic family
grp of organic compounds that have a common structural arrangemenet of atoms (functional grp)
members of the same org family have similar phys and chem properties
examples of functiona groups
carbon-carbon multi bonds (triple, double)
single bonds between carbon and other electronegative elements
carbon dbl bond to oxygen
what is the structural formula look like vs line structural formlua
structural formula: all the carbons and hydrogens are drawn with branches
Line: shows no elements just a line, all corners in the line are carbons. all assume to have max hydrogrens
what is a substituent
a branch
What are the prefixes for the length
meth
eth
prop
but
pent
hex
hept
oct
non
dec
undec
dodec
Nomanclature for hydrocarbons
always list the branches in alpha order (ethyl before methyl)
write the position num then a dash then the length (5 - ethyloctane)
use di, tri, tetra more than 1 of the same type of branch exists
(2,2-dimethyl-4-propyloctane)
cycloalkane and nomanclature
ring structure
write cyclo before the length prefix
Ring is parent chain unless the substituent has more carbons
if only 1 branch, number is unnecessary
if 2 branches list in alpha order, give 1 to first name group
(1 - ethyl-3- methylcyclopentane)
if there is more then 2 branches, list in alpha, make sure all nums are lowest possible
alkane phys prop
all non polar
not soluble in water
are soluble in benzene and non polar things
What is size to boiling point in alkanes
1-4 Carbons - Below 30 C
5-16 Carbons - 30-275 C
16-22 Carbons -Over 250 C
Over 18 Carbons - Over 400 C
Over 26 Carbons - Over 500 C
Chem prop of alkanes
low reactivity (C-C bonds are stable and hard to break)
Gas alkanes are explosive
liqud alkanes are highly fammmable