Hydrocarbons Flashcards

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1
Q

what are aliphatic hydrocarbons ?

A

they are hydrocarbons which do not contain a benzene ring

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2
Q

what are Aromatic hydrocarbons

A

Hydrocarbons that do contain a benzene ring

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3
Q

methane is an example of which kind of hydrocarbon

A

aliphatic(one which does not contain a benzene ring)

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4
Q

what are some general ideas about methane

A

Green house gas with a higher warming potential then that of CO2

it is however very short lived and if action is taken to reduce these emmisions then rapid reducation is global warming will be seen

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5
Q

what are alkanes

A

single bond aliphatic hydrocarbons which have a low molecular wt and are able to solubilize fats this causes toxic effects , they may also be off higher molcular wieght in which case they are much less toxic

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6
Q

What is Narcosis

A

The state of arrested activity of protoplasmic structure , this process is reversibke and non specifci mode of action

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7
Q

What are alkenes

A

also known as Olefins and aliphatic which contain astealst a single double bond, these a more reactive than alkanes but still less then aromatics.

These are found in refined petrolem products

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8
Q

what are some general characteristics of Benzene

A

Presucuro to many chemiacls such as pesticides and solvents, can also be found as a fuel additive.

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9
Q

what are the toxic effects of benzene

A

Incorperateion of oxygen into the ring during degradation gives rise to an epocide intermendate which is long lived within cells, these intermeidated can react with nucleophils, damage to blood cells, lymph and kidney fucntion.

These can lead to cancer

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10
Q

what is toluene

A

Used to make benzene however can also act as a substitute for benzene

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11
Q

what are some harmful effects of toluene

A

Toluene is less soluble in water making it lipophilic meaning that it rapidly reachs the site of action and therefore has a higher potential for toxicity

Greater depressive CNS effect then that seen in benzene

Rapidly degrated when compared to benze therefore less overall effect

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12
Q

Xylene

A

Aromatic hydrocarbon which is virtually insouble in water making it easily transferable in lipid bylayers,

the low water solubility makes it reativly low in toxicity and is therefore often used to replace both benzene and toulene in may instances

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13
Q

some negative health effects of xylene

A

in high conc headaces and imparired coordination edema and nasusea

low conc- chorinc skin irritations anemia blood damage

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14
Q

what is a PAH

A

Polycyclic aromatic hydrocarbons which are colourless white or green solids which are often found attached to PM. these compounds are not easily dissivled into water however will be rapidly evaporated into air

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15
Q

formation of PAH

A

formed through incomplete combustion, few are used in medicines and dyes

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16
Q

the uptake and health effects of PAH

A

uptake– main from inhalation and dermal exposire , remeber that the lower the MC the faster it is taken up

Effect- general irritation on expsoure site, headaces nausea damage to redblood cells as well as kidyneys

The envoirnmental fat – enter envoirnment to air can also evapourate into the air,this is broken down by sunlight

17
Q

Low MC PAHs vs High MC PAHs

A

Low- tent to be more toxic and then to be found in the air more

High- tend to be more carcinogenic and associated wiith soilds such as PM

18
Q

EPT index

A

biotic index which incopeorates response to envoirmental quaility

Measure of envoirmental quaility based on richness of Mayflies stoneflies and caddishflies

19
Q

what are PCBs

A

Polychlorinated biphenyls
- associated with manufactured products, these are no longer produced

20
Q

what are CDDs

A

Chlorinated Dibenzo-p-dioxins which are anthropogenci and natrual sources

21
Q

what are CDFs

A

Chlorinated dibenxofurans
- same as CDDs come form natrual sources and anthropogenic

22
Q

what is found to be the most toxic Dioxins

A

TCDD- which extreamly persistent , while no longer in use most of the current exposure is from historical use

23
Q

toxicity assocated with CDD or dioxins

A

Varries with the number of chlorines and there position in the aromatic ring

24
Q
A