HSAB principle Flashcards
characteristics of soft acids
high electronegativity (for metals), large size (for metals)
characteristics of soft bases
moderate electronegativity (for main group), large size (for main group)
characteristics of soft bases
high electronegativity, small size
characteristics of hard acids
low electronegativity, small size
soft acids occur in nature as ?
chlorides, bromides, iodides, sulfides, selenides, arsenides
grignard reagent
XMgF
softest acid
Au
further from Au the ?(harder/softer) the acid
softer
the smaller the metal ion, the (harder/softer) the acid
harder
the higher the oxidation state, the (harder/softer) the acid
harder
hard bases
O, F
borderline bases
N, Cl
soft bases (not softest)
S, Br
softest bases
C, P, As, Se, Te, I
hard acids
groups 1-6, actinides, lanthanides, B, Al, Si, Ga, Ge